Coordination chemistry of 2,4′-bipyridine.: Synthesis and structures of Co(2,4′- bipyridine)2(NO3)2(H2O) and Cd(2,4′-bipyridine)2(NO3)2(H2O)2

Synthesis and characterization of two coordination complexes of 2,4'-bipyridine, Co(2,4'-bipyridine)(2)(NO3)(2)(H2O) (1), and Cd(2,4'-bipyridine)(2)(NO3)(2)(H2O)(2) (2), are described. Complex 1 was obtained by reacting Co(NO3)(2) . 6H(2)O and 2,4'-bipyridine in a mixture of water and ethanol at room temperature, while 2 was synthesized from Cd(NO3)(2) . 4H(2)O and 2,4'-bipyridine under hydro(solvo)thermal conditions at 90 degrees C. In both complexes the metal centers only coordinate to the il -pyridyl nitrogen atoms of the 2,4'-bipyridine ligands, with the rest of the coordination sites occupied by nitrate groups and water molecules. In 1, the 2-pyridyl nitrogen atoms of the 2,4'-bipyridine ligands form intermolecular hydrogen bonds with both hydrogen atoms of the coordinated water molecule, resulting in a two-dimensional (2-D) polymeric network. In 2, all the hydrogen atoms of the two coordinated water molecules are engaged in intermolecular hydrogen bonding with the 2-pyridyl nitrogen atoms of the 2,4'-bipyridine ligands and the oxygen atoms of the coordinated nitrate group; a 2-D hydrogen-bonded polymeric network is also obtained. Complexes 1 and 2 are the first coordination complexes of 2,4'-bipyridine to be characterized by X-ray crystallography. (C) 1999 Elsevier Science S.A. All rights reserved.