Effect of lanthanum content on the thermophysical properties and near-infrared reflection properties of lanthanum-cerium oxides

被引:6
作者
Zeng, Shenghao [1 ]
Wang, Zhoufu [1 ]
Ma, Yan [1 ]
Wang, Xitang [1 ]
Liu, Hao [1 ]
Dong, Yunjie [1 ]
Li, Yueying [1 ]
Qiao, Entao [1 ]
Qian, Weilun [1 ]
机构
[1] Wuhan Univ Sci & Technol, State Key Lab Refractories & Met, Wuhan 430081, Peoples R China
基金
中国国家自然科学基金;
关键词
Lanthanum-cerium oxides; Lattice distortion; Thermal conductivity; Near-infrared reflectivity; High-temperature energy saving; THERMAL-CONDUCTIVITY; PHASE; PERFORMANCE; EMISSIVITY; STABILITY; RADIATION; COATINGS; ZIRCONIA; LA2CE2O7; CEO2;
D O I
10.1016/j.solidstatesciences.2021.106805
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of lanthanum-cerium oxides with different lanthanum content were synthesized by low-temperature solid-state method, and the effect of lanthanum content on the thermal conductivity and near-infrared reflectance of lanthanum-cerium oxide ceramics was systematically investigated. The results indicated that the thermal conductivity of lanthanum-cerium oxide ceramics decreased significantly with the increase of lanthanum content, which was mainly due to the non-negligible phonon scattering caused by the increased point defects in the structure. Lanthanum-cerium oxide ceramics with different lanthanum content had high near-infrared reflectivity (82%) between 1200 and 2200 nm. The lanthanum-cerium oxide ceramics prepared in this work has lower thermal conductivity and higher near-infrared reflectivity, which has broad application prospects in the field of high-temperature energy saving as thermal insulation material.
引用
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页数:7
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