Structure of mixed matrix membranes made with SAPO-5 zeolite in polyurethane matrix

SAPO-5 zeolite has been used to modify the structure of polyurethane membranes and to improve their properties. Scanning electron microscopy (SEM), Fourier Transform Infrared spectroscopy (FTIR), Bubble-point test, water permeability, swelling in water and several alcohols (methanol, ethanol, I-propanol and I-butanol) and density measurements have been used to study the incorporation of SAPO-5 zeolite in polyurethane membranes, the changes Of Supramolecular structure Of polyurethane in the membrane network and the structural uniformity of the obtained membranes. As a function of the preparation method, anisotropic membranes can be obtained. The incorporation of SAPO-5 zcolite in polyurethane matrix also induces changes in the membrane morphology. The zeolite plays a cross-linking function in the membrane structure. All the tested membranes show a tendency to swell with ethanol. (C) 2008 Elsevier Inc. All rights reserved.