Pb(II) Coordination Polymer Based on Mixed Ligands: Syntheses, Structures, Photoluminescence, and Photocatalysis

被引:9
作者
Li, Xiu-Ying [1 ,2 ]
Gao, Lin [3 ]
Niu, Yue-Qi [4 ]
Liu, Chun-Bo [3 ]
Che, Guang-Bo [2 ,3 ]
Yan, Yong-Sheng [3 ]
Guan, Qing-Feng [1 ]
机构
[1] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China
[2] Jilin Normal Univ, Chinese Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Siping 136000, Peoples R China
[3] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
[4] Jilin Entry Exit Inspect & Quarantine Bur, Hunchun, Peoples R China
基金
中国国家自然科学基金;
关键词
Pb(II) coordination polymer; Benzene-1,4-dioxyacetic acid; 10,11,12,13-Tetrahydro-4,5,9,14-tetraaza-benzo[b]triphenylene; Crystal structure; Photocatalytic activity; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESES; SORPTION PROPERTIES; CRYSTAL-STRUCTURES; AUXILIARY LIGAND; METHYLENE-BLUE; COMPLEXES; ACID; NETWORK; ZN(II);
D O I
10.1007/s10904-015-0182-9
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A new coordination polymer [Pb(ttbt)(1,4-bdoa)](n)center dot 2nH(2)O (1) (1,4-H(2)bdoa = benzene-1,4-dioxyacetic acid and ttbt = 10,11,12,13-tetrahydro-4,5,9,14-tetraaza-benzo[b]triphenylene) has been obtained under hydrothermal conditions. The structure of polymer 1 has been determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, infrared spectra (IR), powder X-ray diffraction (PXRD) and diffuse-reflectance UV-vis spectrum. Polymer 1 displays a one-dimensional chain structure, which is further extended into a two-dimensional layer structure through pi-pi stacking interactions and hydrogen-bonding interactions. The photoluminescence behavior of polymer 1 was also discussed in paper. Meanwhile, polymer 1 represents good performance for the photocatalytic degradation of organic dyes under UV irradiation.
引用
收藏
页码:886 / 891
页数:6
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