Metal precipitation in one-dimensional crystal of CsMnCl3 center dot 2H(2)O

被引：1

作者：

Yoshinari, T

Matsuyama, T

Shimanuki, S

Yamaoka, H

Ohnishi, A

Yamada, T

Aoyagi, K

Kamikawa, T

机构：

[1] KYOTO UNIV,INST RES REACTOR,KUMATORI,OSAKA 59004,JAPAN

[2] OSAKA WOMENS UNIV,SAKAI,OSAKA 590,JAPAN

[3] KYOTO UNIV,DEPT POLYMER CHEM,KYOTO 60601,JAPAN

来源：

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS | 1996年 / 116卷 / 1-4期

关键词：

D O I：

10.1016/0168-583X(96)00133-4

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

Visible metal precipitation of a golden luster has been observed in CsMnCl3 . 2H(2)O which was irradiated with X- or gamma-rays at room temperature. It does not occur when it is irradiated at 77 K and then warmed to room temperature. A continuous optical absorption was observed ranging from 2 eV to higher energy more than 5.50 eV (225 nm), An absorption band overlaps at 3.55 eV (350 nm), which is nearly the same as those of the V-k center (Cl-2(-)) in KCl and RbCl. It suggests that the 3.55 eV band originates from the self-trapped hole centers (Cl-2(-)) in the present crystal.

引用

页码：554 / 557

页数：4

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