Fused hexacyclic tin compounds derived from 3-(3,5-di-t-butyl-2-hydroxy-phenylimino)-3H-phenoxazin-2-ol

被引:8
作者
Camacho-Camacho, Carlos
Esparza-Ruiz, Adriana [1 ]
Vasquez-Badillo, Aurora [1 ]
Noeth, Heinrich [2 ]
Flores-Parra, Angelina [1 ]
Contreras, Rosalinda [1 ]
机构
[1] CINVESTAV, Dept Quim, Mexico City 07000, DF, Mexico
[2] Univ Munich, Dept Chem, D-81377 Munich, Germany
关键词
Fused hexacyclic diorganyltin compounds; X-ray structure; DIBENZOBICYCLIC PHOSPHORANE; ORGANOTIN COMPOUNDS; REACTIVITY; COMPLEXES; NMR; STEREOCHEMISTRY; DERIVATIVES; CHEMISTRY; BRUSSELS; BINDING;
D O I
10.1016/j.jorganchem.2008.11.070
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The template synthesis of two tin compounds [N -> Sn] 3-(2-oxo-phenylimino)-3H-phenoxazin-2-oxodimethyltin (1) and [N -> Sn] 3-(2-oxo-phenylimino)-3H-phenoxazin-2-oxo-diphenyltin (2) is reported. The compounds are fused delocalized planar hexacyclic systems bearing a pentacoordinated diorganyl tin. They were identified by NMR, IR, TOF mass spectra and, for compound 1, by X-ray diffraction analysis. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:726 / 730
页数:5
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