Fluorescent chemosensor;
9-(Cycloheptatrienylidene)fluorene;
NOR logic gate;
Photoinduced electron transfer;
Intramolecular charge transfer;
Off-on-off;
D O I:
10.1016/j.snb.2008.05.019
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
Novel fluorescenct chemosensors for Cu2+ and Fe3+ based on 9-(cycloheptatrienylidene)fluorene derivatives (I and 2) were prepared and characterized. I displayed quenched emission when either Cu2+ or Fe3+ was added into its acetonitrile solution, while 2 could successfully identify Fe3+ or Cu2+ by enhanced emission with addition of Fe3+ in its methanol or with addition of Cu2+ in its acetonitrile solution. (C) 2008 Elsevier B.V. All rights reserved.