Synthesis and characterization of 9-(cycloheptatrienylidene)fluorene derivatives: New fluorescent chemosensors for detection of Fe3+ and Cu2+

被引:24
作者
Jiang, Zhitao [1 ]
Tang, Lei [1 ]
Shao, Fei [1 ]
Zheng, Guorong [1 ]
Lu, Ping [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
基金
中国国家自然科学基金;
关键词
Fluorescent chemosensor; 9-(Cycloheptatrienylidene)fluorene; NOR logic gate; Photoinduced electron transfer; Intramolecular charge transfer; Off-on-off;
D O I
10.1016/j.snb.2008.05.019
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Novel fluorescenct chemosensors for Cu2+ and Fe3+ based on 9-(cycloheptatrienylidene)fluorene derivatives (I and 2) were prepared and characterized. I displayed quenched emission when either Cu2+ or Fe3+ was added into its acetonitrile solution, while 2 could successfully identify Fe3+ or Cu2+ by enhanced emission with addition of Fe3+ in its methanol or with addition of Cu2+ in its acetonitrile solution. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:414 / 418
页数:5
相关论文
共 25 条
[11]   1-and 2-naphthylmethyl sidearms of isomeric bibracchial lariat ethers significantly affect alkali metal cation complexation [J].
Meadows, ES ;
De Wall, SL ;
Barbour, LJ ;
Gokel, GW .
CHEMICAL COMMUNICATIONS, 1999, (16) :1555-1556
[12]  
Michael S., 1996, ANAL CHEM, V68, P1414
[13]   Modular fluorescent-labeled siderophore analogues [J].
Nudelman, R ;
Ardon, O ;
Hadar, Y ;
Chen, YN ;
Libman, J ;
Shanzer, A .
JOURNAL OF MEDICINAL CHEMISTRY, 1998, 41 (10) :1671-1678
[14]   A selective and sensitive fluoroionophore for HgII, AgI, and CuII with virtually decoupled fluorophore and receptor units [J].
Rurack, K ;
Kollmannsberger, M ;
Resch-Genger, U ;
Daub, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (05) :968-969
[15]   Charge propagation in "ion channel sensors" based on protein-modified electrodes and redox marker ions [J].
Schön, P ;
Degefa, TH ;
Asaftei, S ;
Meyer, W ;
Walder, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (32) :11486-11496
[16]   The copper-iron connection in biology: Structure of the metallo-oxidase Fet3p [J].
Taylor, AB ;
Stoj, CS ;
Ziegler, L ;
Kosman, DJ ;
Hart, PJ .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2005, 102 (43) :15459-15464
[17]   Selective metal ion recognition using a fluorescent 1,8-diquinolylnaphthalene-derived sensor in aqueous solution [J].
Tumarnbac, GE ;
Rosencrance, CM ;
Wolf, C .
TETRAHEDRON, 2004, 60 (49) :11293-11297
[18]   Design principles of fluorescent molecular sensors for cation recognition [J].
Valeur, B ;
Leray, I .
COORDINATION CHEMISTRY REVIEWS, 2000, 205 :3-40
[19]   9-(Cycloheptatrienylidene)-fluorene derivative: Remarkable ratiometric pH sensor and computing switch with NOR logic gate [J].
Wang, ZX ;
Zheng, GR ;
Lu, P .
ORGANIC LETTERS, 2005, 7 (17) :3669-3672
[20]   Synthesis and characterization of 9-(cycloheptatrienylidene)fluorene derivatives: Acid-triggered "Switch on" of fluorophores [J].
Wang, ZX ;
Xing, YJ ;
Shao, HX ;
Lu, P ;
Weber, WP .
ORGANIC LETTERS, 2005, 7 (01) :87-90