Synthesis and characterization of 9-(cycloheptatrienylidene)fluorene derivatives: New fluorescent chemosensors for detection of Fe3+ and Cu2+

被引:24
作者
Jiang, Zhitao [1 ]
Tang, Lei [1 ]
Shao, Fei [1 ]
Zheng, Guorong [1 ]
Lu, Ping [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源
SENSORS AND ACTUATORS B-CHEMICAL | 2008年 / 134卷 / 02期
基金
中国国家自然科学基金;
关键词
Fluorescent chemosensor; 9-(Cycloheptatrienylidene)fluorene; NOR logic gate; Photoinduced electron transfer; Intramolecular charge transfer; Off-on-off;
D O I
10.1016/j.snb.2008.05.019
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Novel fluorescenct chemosensors for Cu2+ and Fe3+ based on 9-(cycloheptatrienylidene)fluorene derivatives (I and 2) were prepared and characterized. I displayed quenched emission when either Cu2+ or Fe3+ was added into its acetonitrile solution, while 2 could successfully identify Fe3+ or Cu2+ by enhanced emission with addition of Fe3+ in its methanol or with addition of Cu2+ in its acetonitrile solution. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:414 / 418
页数:5
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