Cyclic Polymers: Methods and Strategies

被引：238

作者：

Jia, Zhongfan ^{[1
]}

Monteiro, Michael J. ^{[1
]}

机构：

[1] Univ Queensland, Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2012年 / 50卷 / 11期

关键词：

addition polymerization; cyclopolymerization; Click'' chemistry; CuAAC; kinetics; living radical polymerization; macrocycles; macrocyclics; LIQUID-CRYSTALLINE POLYETHERS; RING-OPENING POLYMERIZATION; EXPANSION METATHESIS POLYMERIZATION; DILUTE-SOLUTION CHARACTERIZATION; TRANSFER RADICAL POLYMERIZATION; MACROCYCLIC GRAFT COPOLYMER; CHAIN COMPETITION KINETICS; POLYSTYRENE LATERAL CHAINS; AMMONIUM-SALT GROUPS; CLICK-CHEMISTRY;

D O I：

10.1002/pola.25999

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Cyclic polymers have different physical properties compared to their linear counterparts of the same molecular weight. These different properties could have potential impact in the production of new and exciting polymer products. For industry to commercialize such materials, cyclic polymers need to be made on large scales, have controlled molecular weight distributions, and have versatile chemical composition. This highlight article describes many of the synthetic methods and strategies for obtaining highly pure cyclic polymers, and presents kinetic attributes for some of the processes. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 50: 2085-2097, 2012

引用

页码：2085 / 2097

页数：13

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