Two Isomeric Magnesium Metal-Organic Frameworks with [24-MC-6] Metallacrown Cluster

被引：36
作者：
Han, Lei [1 ]
Qin, Lan [1 ]
Yan, Xiao-Zhi [1 ]
Xu, Lan-Ping [1 ]
Sun, Junliang [2 ]
Yu, Lei [1 ]
Chen, Hong-Bing [1 ]
Zou, Xiaodong [2 ]
机构：
[1] Ningbo Univ, Fac Chem Engn & Mat Sci, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China
[2] Stockholm Univ, Dept Mat & Environm Chem, Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden
来源：
CRYSTAL GROWTH & DESIGN | 2013年 / 13卷 / 05期
基金：
瑞典研究理事会; 中国国家自然科学基金;
关键词：
CARBON-DIOXIDE; SUPRAMOLECULAR ISOMERS; COORDINATION POLYMERS; SEPARATION; PORES; CATENATION; ADSORPTION; CHEMISTRY; NETWORKS; TOPOLOGY;
D O I：
10.1021/cg4000318
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two novel Mg-based metal-organic framework isomers with the formula [Mg-2(HCO2)(2)(NH2-BDC)-(DMF)(2)](n) (NH2-BDC = 2-amino-1,4-benzenedicarboxylate) have been synthesized based on a 6-connected [24-MC-6] metallacrown secondary building unit (SBU), which display a two-dimensional (2D) 3(6) net (1) and three-dimensional primitive rhombohedral net (2) derived from a different extended orientation of SBU, respectively. The 2D framework of 1 exhibits relevant thermal stability, solvents stability, high CO2 adsorption, and strong luminescent properties.
引用
收藏
页码：1807 / 1811
页数：5
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