Spectroscopic characteristic and energy levels of Cr3+ in Cr3+:KAl(MoO4)2 crystal

被引:22
|
作者
Wang, Gujian [1 ,2 ]
Long, Xifa [1 ]
Zhang, Lizhen [1 ]
Wang, Guofu [1 ]
Polosan, Silviu [3 ]
Tsuboi, Taiju [3 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] Kyoto Sangyo Univ, Fac Engn, Kita Ku, Kyoto 6038555, Japan
基金
中国国家自然科学基金;
关键词
polarized spectral properties; energy levels; Cr2+: KAl(MoO4)(2) crystal;
D O I
10.1016/j.jlumin.2008.03.004
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
This paper reports polarized spectral properties and energy levels of Cr3+ in KAl(MoO4)(2) crystal. The absorption and emission cross sections are estimated as 3.72 x 10(-21) cm(2) at 669 nm and 2.74 x 10(-20) cm(-2) at 823 nm for sigma-polarization, respectively. The energy levels of Cr3+ ion in KAl(MoO4)(2) crystal were calculated based on the Tanabe-Sugano theory. It is suggested that Cr3+ ions occupy at an intermediate crystal field site in Cr3+:KAl(MoO4)(2). (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1556 / 1560
页数:5
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