Aromatic sulfide, sulfoxide, and sulfone mediated mesoporous carbon monolith for use in supercapacitor

被引：307

作者：

Zhao, Xiaochen ^{[1
,2
,4
]}

Zhang, Qiang ^{[1
,3
]}

Chen, Cheng-Meng ^{[1
,4
]}

Zhang, Bingsen ^{[1
,5
]}

Reiche, Sylvia ^{[1
]}

Wang, Aiqin ^{[2
]}

Zhang, Tao ^{[2
]}

Schloegl, Robert ^{[1
]}

Su, Dang Sheng ^{[1
,5
]}

机构：

[1] Max Planck Gesell, Fritz Haber Inst, Dept Inorgan Chem, D-14195 Berlin, Germany

[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[3] Tsinghua Univ, Dept Chem Engn, Beijing Key Lab Green Chem React Engn & Technol, Beijing 100084, Peoples R China

[4] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

[5] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China

来源：

NANO ENERGY | 2012年 / 1卷 / 04期

关键词：

Sulfur; Mesoporous carbon; Supercapacitor; Monolith; OXIDATIVE DEHYDROGENATION; ELECTROCHEMICAL PERFORMANCE; ACTIVATED CARBON; FOSSIL-FUELS; NITROGEN; NANOTUBES; BIODIESEL; CATALYSTS; ENERGY; NANOFIBERS;

D O I：

10.1016/j.nanoen.2012.04.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Monoliths of aromatic sulfur mediated mesoporous carbon were fabricated via an aqueous self-assembly strategy and the species of sulfide, sulfoxide, and sulfone on the surface can be tuned rationally. The resultant S-doped mesoporous carbon exhibited superior performance as supercapacitor electrodes. The controllable modulation of sulfur species provided a possibility to clearly understand the role sulfur playing and allowed mechanistic insight into material requirements for high performance capacitors. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：624 / 630

页数：7

共 63 条

[1] Tuning the Acid/Base Properties of Nanocarbons by Functionalization via Amination [J].

Arrigo, Rosa ;

Haevecker, Michael ;

Wrabetz, Sabine ;

Blume, Raoul ;

Lerch, Martin ;

McGregor, James ;

Parrott, Edward P. J. ;

Zeitler, J. Axel ;

Gladden, Lynn F. ;

Knop-Gericke, Axel ;

Schloegl, Robert ;

Su, Dang Sheng .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (28) :9616-9630

[2] Nanostructured carbons in catalysis a Janus material-industrial applicability and fundamental insights [J].

Bitter, J. H. .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (35) :7312-7321

[3] SOME ASPECTS OF THE SURFACE-CHEMISTRY OF CARBON-BLACKS AND OTHER CARBONS [J].

BOEHM, HP .

CARBON, 1994, 32 (05) :759-769

[4] Surface oxides on carbon and their analysis: a critical assessment [J].

Boehm, HP .

CARBON, 2002, 40 (02) :145-149

[5] Ordered mesoporous silicas and carbons with large accessible pores templated from amphiphilic diblock copolymer poly(ethylene oxide)-b-polystyrene [J].

Deng, Yonghui ;

Yu, Ting ;

Wan, Ying ;

Shi, Yifeng ;

Meng, Yan ;

Gu, Dong ;

Zhang, Lijuan ;

Huang, Yan ;

Liu, Chong ;

Wu, Xiaojing ;

Zhao, Dongyuan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (06) :1690-1697

[6] Sulfurization of carbon surface for vapor phase mercury removal - I: Effect of temperature and sulfurization protocol [J].

Feng, Wenguo ;

Borguet, Eric ;

Vidic, Radisav D. .

CARBON, 2006, 44 (14) :2990-2997

[7] The role of surface chemistry in catalysis with carbons [J].

Figueiredo, Jose Luis ;

Pereira, Manuel Fernando R. .

CATALYSIS TODAY, 2010, 150 (1-2) :2-7

[8] Carbon materials for the electrochemical storage of energy in capacitors [J].

Frackowiak, E ;

Béguin, F .

CARBON, 2001, 39 (06) :937-950

[9] Oxidative Dehydrogenation of Ethane over Multiwalled Carbon Nanotubes [J].

Frank, Benjamin ;

Morassutto, Mattia ;

Schomaecker, Reinhard ;

Schloegl, Robert ;

Su, Dang Sheng .

CHEMCATCHEM, 2010, 2 (06) :644-648

[10] Heteroatoms Increase the Selectivity in Oxidative Dehydrogenation Reactions on Nanocarbons [J].

Frank, Benjamin ;

Zhang, Jian ;

Blume, Raoul ;

Schloegl, Robert ;

Su, Dang Sheng .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (37) :6913-6917

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