Novel isoindigo-based conjugated polymers for solar cells and field effect transistors

被引：32

作者：

Mahmood, Khalid ^{[1
]}

Liu, Zheng-Ping ^{[1
]}

Li, Cuihong ^{[1
]}

Lu, Zhen ^{[1
]}

Fang, Tao ^{[1
]}

Liu, Xiao ^{[1
]}

Zhou, Jianjun ^{[1
]}

Lei, Ting ^{[2
]}

Pei, Jian ^{[2
]}

Bo, Zhishan ^{[1
]}

机构：

[1] Beijing Normal Univ, Coll Chem, Beijing Key Lab Energy Convers & Storage Mat, Beijing 100187, Peoples R China

[2] Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

POLYMER CHEMISTRY | 2013年 / 4卷 / 12期

关键词：

BAND-GAP POLYMERS; DESIGN RULES; DONOR; EFFICIENCY; COPOLYMERS;

D O I：

10.1039/c3py00341h

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Three new isoindigo containing donor-acceptor (D-A) type conjugated polymers were synthesized by palladium catalyzed Suzuki polycondensation and used as donor materials for polymer solar cells (PSCs) and field effect transistors (FETs). All the polymers possess good solubility in common organic solvents, high thermal stability, and broad absorption in the range of 300 to 750 nm. These polymers have narrow band gaps (1.66 to 1.70 eV) and low lying HOMO energy levels (5.15 to 5.31 eV). Hole mobilities of these polymers are in the range of 1.78 x 10 (-)3 to 2.62 x 10(-3) cm(2) V-1 s(-1). PSCs based on P3:PC71BM (1 : 2, by weight) gave the best device performance with a power conversion efficiency (PCE) of 1.75%, a short-circuit current density (J(sc)) of 4.74 mA cm(-2), an open-circuit voltage (V-oc) of 0.81 V, and a fill factor (FF) of 0.45, indicating these polymers can be promising donor polymers for polymer solar cells.

引用

页码：3563 / 3574

页数：12

共 50 条

[1] Donor-acceptor type low band gap polymers: polysquaraines and related systems
Ajayaghosh, A
[J]. CHEMICAL SOCIETY REVIEWS, 2003, 32 (04) : 181 - 191
[2] Dithienogermole As a Fused Electron Donor in Bulk Heterojunction Solar Cells
Amb, Chad M.
Chen, Song
Graham, Kenneth R.
Subbiah, Jegadesan
Small, Cephas E.
So, Franky
Reynolds, John R.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (26) : 10062 - 10065
[3] A low-bandgap poly(2,7-carbazole) derivative for use in high-performance solar cells
Blouin, Nicolas
Michaud, Alexandre
Leclerc, Mario
[J]. ADVANCED MATERIALS, 2007, 19 (17) : 2295 - +
[4] A new poly(2,7-dibenzosilole) derivative in polymer solar cells
Boudreault, Pierre-Luc T.
Michaud, Alexandre
Leclerc, Mario
[J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2007, 28 (22) : 2176 - 2179
[5] Brabec CJ, 2001, ADV FUNCT MATER, V11, P374, DOI 10.1002/1616-3028(200110)11:5<374::AID-ADFM374>3.0.CO
[6] 2-W
[7] Low band gap polymers for organic photovoltaics
Bundgaard, Eva
Krebs, Frederik C.
[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (11) : 954 - 985
[8] Development of Novel Conjugated Donor Polymers for High-Efficiency Bulk-Heterojunction Photovoltaic Devices
Chen, Junwu
Cao, Yong
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) : 1709 - 1718
[9] Design rules for donors in bulk-heterojunction tandem solar cells-towards 15 % energy-conversion efficiency
Dennler, Gilles
Scharber, Markus C.
Ameri, Tayebeh
Denk, Patrick
Forberich, Karen
Waldauf, Christoph
Brabec, Christoph J.
[J]. ADVANCED MATERIALS, 2008, 20 (03) : 579 - +
[10] Polymer-Fullerene Bulk-Heterojunction Solar Cells
Dennler, Gilles
Scharber, Markus C.
Brabec, Christoph J.
[J]. ADVANCED MATERIALS, 2009, 21 (13) : 1323 - 1338

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