The technology of hot-wire electrochemistry

被引：0

作者：

Gründler, P ^{[1
]}

Kirbs, A ^{[1
]}

机构：

[1] Univ Rostock, Dept Chem, D-18051 Rostock, Germany

来源：

ELECTROANALYSIS | 1999年 / 11卷 / 04期

关键词：

hot-wire electrochemistry; heating of the electrode;

D O I：

10.1002/(SICI)1521-4109(199904)11:4<223::AID-ELAN223>3.0.CO;2-3

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The technologic basis for in situ heating of a microelectrode wire by high amplitude, high frequency alternating current (hot-wire electrochemistry) is presented. The preferred modes are continuous heating until a stationary temperature value is established, and pulsed heating with short time current sampling. The latter allows measurement above the boiling point.

引用

页码：223 / 228

页数：6

共 4 条

[1] The limits of aqueous hot-wire electrochemistry:: Near-critical and supercritical fluids in electrochemical sensors?
Gründler, P
Degenring, D
ELECTROANALYSIS, 2001, 13 (8-9) : 755 - 759
[2] Hot-wire amperometric monitoring of flowing streams
Wang, J
Jasinski, M
Flechsig, GU
Grundler, P
Tian, BM
TALANTA, 2000, 50 (06) : 1205 - 1210
[3] Hot-wire electrodes: Voltammetry above the boiling point
Grundler, P
Kirbs, A
Zerihun, T
ANALYST, 1996, 121 (12) : 1805 - 1810
[4] Temperature calculation for pulse-heated hot-wire electrodes
Gründler, P
Degenring, D
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 512 (1-2): : 74 - 82

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