Pillared Porphyrin Homologous Series: Intergrowth in Metal-Organic Frameworks

被引：168
作者：
Choi, Eun-Young [1 ]
Barron, Paul M. [1 ]
Novotny, Richard W. [1 ]
Son, Hyun-Tak [1 ]
Hu, Chunhua [2 ]
Choe, Wonyoung [1 ]
机构：
[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA
[2] NYU, Dept Chem, New York, NY 10003 USA
来源：
INORGANIC CHEMISTRY | 2009年 / 48卷 / 02期
关键词：
MICROPOROUS COORDINATION POLYMERS; SECONDARY-BUILDING UNITS; PADDLE-WHEEL; SELECTIVE SORPTION; HYDROGEN STORAGE; GAS-ADSORPTION; CRYSTAL-STRUCTURE; DESIGN; NETS; MOTIFS;
D O I：
10.1021/ic801677y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We report three new porphyrin-based, pillared paddle-wheel homologous series: porphyrin paddle-wheel frameworks PPF-3, -4, and -5. These compounds are assembled from free base or palladium tetrakis(4-carboxyphenyl)porphine, M(NO3)(2) (M = Co and Zn), and 4,4'-bipyridine via solvothermal reactions. The resulting solids exhibit 3D metal-organic frameworks, where 2D layers are pillared by bipyridine with three different packing arrangements.
引用
收藏
页码：426 / 428
页数：3
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