Redox-Selective Generation of Aldehydes and H2 from Alcohols under Visible Light

被引：34

作者：

Liu, Zijun ^{[1
]}

Caner, Joaquim ^{[1
]}

Kudo, Akihiko ^{[2
]}

Naka, Hiroshi ^{[1
]}

Saito, Susumu ^{[3
,4
]}

机构：

[1] Nagoya Univ, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Tokyo Univ Sci, Fac Sci, Dept Appl Chem, Shinjyuku Ku, Tokyo 1628601, Japan

[3] Nagoya Univ, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[4] Nagoya Univ, Inst Adv Res, Chikusa Ku, Nagoya, Aichi 4648602, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 29期

关键词：

alcohols; aldehydes; dehydrogenation; heterogeneous photosynthesis; visible light; DEHYDROGENATIVE OXIDATION; PHOTOCATALYTIC DEHYDROGENATION; DOPED SRTIO3; WATER; CONVERSION; DRIVEN; NANOPARTICLES; ACCEPTORLESS; DIHYDROGEN; COMPLEXES;

D O I：

10.1002/chem.201301347

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photosynthetic dehydrogenation: Potential usefulness of visible-light-induced dehydrogenation of alcohols in organic synthesis was demonstrated, in which aldehydes and H2 were afforded by using Ru/SrTiO3:Rh and water (see scheme). Water was essential for the reaction. High efficiency (TON: up to 15 400 based on Rh; H2 and aldehyde evenly generated) and high selectivity were achieved. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9452 / 9456

页数：5

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