Synthesis and structure of a new three-dimensional microporous indium arsenate

被引：0

作者：

Chen, ZX ^{[1
]}

Weng, LH ^{[1
]}

Zhou, YM ^{[1
]}

Zhang, HY ^{[1
]}

Zhao, DY ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

ACTA CHIMICA SINICA | 2002年 / 60卷 / 02期

关键词：

microporous material; indium arsenate; hydrothermal synthesis; structure; characterization;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new three-dimensional microporous indium. arsenate has been synthesized for the first time from the hydrothermal reaction of H2O, InCl3 . 4H(2)O, H3AsO4 and C6H12N2 . 6H(2)O. Single crystal X-ray diffraction studies show that it has an orthorhombic (symmetry space group Pbca) with a = 0.9090 (4) nm, b = 1.0344 (4) nm, c = 1.0468(4) nm. It's asymmetry unit is InAsO4(H2O)(2), which produces a 4-ring and 6-ring 1D channel along the a and b axis, respectively. It also contains a cage-like structure surrounded by 4,6,8-rings. The organic amine is not occluded in the structure. This structure is the first indium. arsenate analog of InPO4-1.

引用

页码：305 / 309

页数：5

共 18 条

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