Equilibrium phase diagram of semi-flexible polymer networks with linkers

被引:33
作者
Cyron, C. J. [1 ]
Mueller, K. W. [1 ]
Schmoller, K. M. [2 ]
Bausch, A. R. [2 ]
Wall, W. A. [1 ]
Bruinsma, R. F. [3 ,4 ]
机构
[1] Tech Univ Munich, Inst Computat Mech, D-85748 Garching, Germany
[2] Tech Univ Munich, Lehrstuhl Zellbiophys E27, D-85748 Garching, Germany
[3] Univ Calif Los Angeles, Dept Phys & Astron, Los Angeles, CA 90095 USA
[4] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA 90095 USA
基金
美国国家科学基金会;
关键词
ALPHA-ACTININ; ARCHITECTURE;
D O I
10.1209/0295-5075/102/38003
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We present the determination by numerical simulation of the equilibrium phase diagram of solutions of semi-flexible polymers with linker molecules. At low linker concentrations the solution forms an isotropic gel phase. At higher linker concentrations we encounter-depending on the properties of the linker molecules-bundle phases, liquid-crystalline mesophases with broken bond-orientational order that had been predicted by analytical theories, and in addition a novel equilibrium state: the cluster phase. Equilibrium condensation of semi-flexible polymers appears to be controlled by linker entropy. The results are compared with the phase behavior of solutions of biopolymers and linker proteins. Copyright (C) EPLA, 2013
引用
收藏
页数:6
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