Selective Synthesis of Primary Amines Directly from Alcohols and Ammonia

被引：475

作者：

Gunanathan, Chidambaram ^{[1
]}

Milstein, David ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 45期

基金：

以色列科学基金会;

关键词：

amines; homogeneous catalysis; pincer ligands; ruthenium; synthetic methods;

D O I：

10.1002/anie.200803229

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Air stable and waterproof: Selective and efficient synthesis of primary amines directly from alcohols and ammonia is achieved under mild conditions (see scheme). The reaction is homogenously catalyzed by a novel air-stable ruthenium pincer complex and can proceed in toluene or even in the absence of solvent or "on water". © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8661 / 8664

页数：4

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