Selective Synthesis of Primary Amines Directly from Alcohols and Ammonia

被引：473

作者：

Gunanathan, Chidambaram ^{[1
]}

Milstein, David ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 45期

基金：

以色列科学基金会;

关键词：

amines; homogeneous catalysis; pincer ligands; ruthenium; synthetic methods;

D O I：

10.1002/anie.200803229

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Air stable and waterproof: Selective and efficient synthesis of primary amines directly from alcohols and ammonia is achieved under mild conditions (see scheme). The reaction is homogenously catalyzed by a novel air-stable ruthenium pincer complex and can proceed in toluene or even in the absence of solvent or "on water". © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8661 / 8664

页数：4

共 50 条

[1] Catalytic Oxidative Synthesis of Nitriles Directly from Primary Alcohols and Ammonia
Oishi, Takamichi
Yamaguchi, Kazuya
Mizuno, Noritaka
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (34) : 6286 - 6288
[2] Heterogeneously Catalyzed Synthesis of Primary Amides Directly from Primary Alcohols and Aqueous Ammonia
Yamaguchi, Kazuya
Kobayashi, Hiroaki
Oishi, Takamichi
Mizuno, Noritaka
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (02) : 544 - 547
[3] Heterogeneous Ni Catalyst for Direct Synthesis of Primary Amines from Alcohols and Ammonia
Shimizu, Ken-ichi
Kon, Kenichi
Onodera, Wataru
Yamazaki, Hiroshi
Kondo, Junko N.
ACS CATALYSIS, 2013, 3 (01): : 112 - 117
[4] Oxidative amide synthesis directly from alcohols with amines
Chen, Cheng
Hong, Soon Hyeok
ORGANIC & BIOMOLECULAR CHEMISTRY, 2011, 9 (01) : 20 - 26
[5] Selective Synthesis of Secondary Amines via N-Alkylation of Primary Amines and Ammonia with Alcohols by Supported Copper Hydroxide Catalysts
He, Jinling
Yamaguchi, Kazuya
Mizuno, Noritaka
CHEMISTRY LETTERS, 2010, 39 (11) : 1182 - 1183
[6] Selective monoalkylation of ammonia: A high throughput synthesis of primary amines
Bhattacharyya, S
Neidigh, KA
Avery, MA
Williamson, JS
SYNLETT, 1999, (11) : 1781 - 1783
[7] Selective Synthesis of Primary Amines by Kinetic-based Optimization of the Ruthenium-Xantphos Catalysed Amination of Alcohols with Ammonia
Heider, Christian
Pietschmann, Dominik
Vogt, Dieter
Seidensticker, Thomas
CHEMCATCHEM, 2022, 14 (18)
[8] Iron-Catalyzed Synthesis of Amines and Thioethers Directly from Allylic Alcohols
Wang, Dan-Yang
Peng, Xiao-Min
Wang, Guang-Zhu
Zhang, Ya-Juan
Guo, Tao
Zhang, Pan-Ke
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 7 (05) : 875 - 878
[9] Ammonia surrogates in the synthesis of primary amines
Urbina-Alvarez, Julia
Rincon-Carvajal, Sergio
Gamba-Sanchez, Diego
ORGANIC & BIOMOLECULAR CHEMISTRY, 2023, 21 (35) : 7036 - 7051
[10] Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia
Luo, Jie
Zhou, Quan-Quan
Montag, Michael
Ben-David, Yehoshoa
Milstein, David
CHEMICAL SCIENCE, 2022, 13 (13) : 3894 - 3901

← 1 2 3 4 5 →