Structural, magnetic and electrical properties of Bi doped LaFeO3 nano-crystals, synthesized by auto-combustion method

被引:51
作者
Ahmed, M. A. [1 ]
Azab, A. A. [2 ]
El-Khawas, E. H. [3 ]
机构
[1] Cairo Univ, Fac Sci, Dept Phys, Mat Sci Lab 1, Giza, Egypt
[2] Natl Res Ctr, Div Phys, Dept Solid State Phys, Solid State Elect Lab, Giza 12622, Egypt
[3] Higher Technol Inst, Dept Basic Sci, Tenth Of Ramadan City, Egypt
关键词
DIELECTRIC-PROPERTIES; TEMPERATURE; PERFORMANCE; BEHAVIOR; OXYGEN;
D O I
10.1007/s10854-015-3556-4
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
La1-xBixFeO3; 0 a parts per thousand currency sign x a parts per thousand currency sign 0.2 have been prepared by citrate auto-combustion method. The results of X-ray diffraction showed that LaFeO3 has single phase with orthorhombic structure. With increasing Bi content, traces of secondary phase of rhombohedral structure are observed. The transmission electron microscope showed that the prepared compositions have nanocrystalline structure with an increase of the particle size increases with increasing Bi content. The magnetic properties of the samples were investigated by vibrating sample magnetometer, in which saturation magnetization (M-s) and coercivity (H-c) were determined. The value of Ms increases with increasing Bi content up to x = 0.10, while H-c decreases with increasing Bi content. The temperature dependence of dielectric constant, dielectric loss and ac conductivity at different frequencies (100 kHz-5 MHz) were studied.
引用
收藏
页码:8765 / 8773
页数:9
相关论文
共 47 条
[1]   Exchange bias in LaFeO3 nanoparticles [J].
Ahmadvand, Hossein ;
Salamati, Hadi ;
Kameli, Parviz ;
Poddar, Asok ;
Acet, Mehmet ;
Zakeri, Khalil .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2010, 43 (24)
[2]   Novel structural and magnetic properties of Mg doped copper nanoferrites prepared by conventional and wet methods [J].
Ahmed, M. A. ;
Afify, H. H. ;
El Zawawia, I. K. ;
Azab, A. A. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2012, 324 (14) :2199-2204
[3]  
Azab A, 2013, J APPL SCI RES, V9, P1683
[4]   Structural and magnetic properties of La1-xCexFe1-xCrxO3 orthoferrite prepared by co-precipitation method [J].
Azab, A. A. ;
Helmy, N. ;
Albaaj, Sukrat .
MATERIALS RESEARCH BULLETIN, 2015, 66 :249-253
[5]   Synthesis and measurement of structural and magnetic properties of K-doped LaCoO3 perovskite materials [J].
Bellakki, Manjunath B. ;
Madhu, C. ;
Greindl, Tobias ;
Kohli, Sandeep ;
McCurdy, Patrick ;
Manivannan, V. .
RARE METALS, 2010, 29 (05) :491-500
[6]   Structural, electrical and ethanol sensing properties of double-doping LaFeO3 perovskite oxides [J].
Benali, A. ;
Azizi, S. ;
Bejar, M. ;
Dhahri, E. ;
Graca, M. F. P. .
CERAMICS INTERNATIONAL, 2014, 40 (09) :14367-14373
[7]   Effect of Zn doping on structural, magnetic and dielectric properties of LaFeO3 synthesized through sol-gel auto-combustion process [J].
Bhat, Irshad ;
Husain, Shahid ;
Khan, Wasi ;
Patil, S. I. .
MATERIALS RESEARCH BULLETIN, 2013, 48 (11) :4506-4512
[8]   OXYGEN-ION MIGRATION IN PEROVSKITE-TYPE OXIDES [J].
CHERRY, M ;
ISLAM, MS ;
CATLOW, CRA .
JOURNAL OF SOLID STATE CHEMISTRY, 1995, 118 (01) :125-132
[9]   ON THE SYSTEMATIC SELECTION OF PEROVSKITE SOLID ELECTROLYTES FOR INTERMEDIATE TEMPERATURE FUEL-CELLS [J].
COOK, RL ;
SAMMELLS, AF .
SOLID STATE IONICS, 1991, 45 (3-4) :311-321
[10]   Hydrogen production from a combination of the water-gas shift and redox cycle process of methane partial oxidation via lattice oxygen over LaFeO3 perovskite catalyst [J].
Dai, Xiao Ping ;
Wu, Qiong ;
Li, Ran Jia ;
Yu, Chang Chun ;
Hao, Zheng Ping .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (51) :25856-25862