Synthesis and Properties of Hydrazino Amino Acyclic Carbenes of Gold(I), Platinum(II), Palladium(II) and Rhodium(III)

被引：24

作者：

Tsupova, Svetlana ^{[1
]}

Rudolph, Matthias ^{[1
]}

Rominger, Frank ^{[1
]}

Hashmi, A. Stephen K. ^{[1
,2
]}

机构：

[1] Heidelberg Univ, Organ Chem Inst, Neuenheimer Feld 270, D-69120 Heidelberg, Germany

[2] KAU, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2016年 / 358卷 / 24期

关键词：

carbene ligands; cyclization; gold; homogeneous catalysis; hydrazines; N-HETEROCYCLIC CARBENES; TRANSITION-METAL-COMPLEXES; DIAMINOCARBENE LIGANDS; CATALYTIC-ACTIVITY; PROPARGYLIC AMIDES; COPPER-FREE; REACTIVITY; CYCLOISOMERIZATION; DERIVATIVES; CYCLIZATION;

D O I：

10.1002/adsc.201600615

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The nucleophilic addition of protected and substituted hydrazine derivatives to isonitrile complexes of gold(I), platinum(II), palladium(II) and rhodium(III) provides the corresponding hydrazino amino acyclic carbene complexes. These are characterized by their spectroscopic data, four different X-ray single crystal structure analyses and their catalytic activity in the gold(I)-catalyzed cycloisomerization of N-propargylcarboxamides to alkylideneoxazolines is investigated.

引用

页码：3999 / 4005

页数：7

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