The development of a new catalytic process:: Bu3SnH-catalyzed reductive cyclization of enals and enones

被引:22
作者
Hays, DS [1 ]
Fu, GC [1 ]
机构
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
关键词
catalysis; cyclisation; silicon and compounds; tin and compounds;
D O I
10.1016/S0040-4020(99)00446-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
By sequencing two known reactions, a new catalytic carbon-carbon bond-forming process, the Bu3SnH-catalyzed, PhSiH3-mediated reductive cyclization of enals and enones, has been developed. The addition of EtOH to the reactions leads to reproducibly good yields of the cyclized products; a rationale for including this additive is provided. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:8815 / 8832
页数:18
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