Synthesis and electrochemical performances of layered NaLi0.2Ni0.2Mn0.6O2 cathode for sodium-ion batteries

被引:17
|
作者
Nguyen Van Nghia [1 ]
Ou, Pao-Wei [1 ]
Hung, I-Ming [1 ]
机构
[1] Yuan Ze Univ, Dept Chem Engn & Mat Sci, Taoyuan 320, Taiwan
关键词
Batteries; Electrodes; Transition-metal oxides; Solid-state reaction; MANGANESE OXIDE; THERMAL-PROPERTIES; HIGH-POWER; INTERCALATION; INSERTION/DEINSERTION; ALPHA-NAFEO2; NA0.44MNO2; INSERTION; BEHAVIOR; P2-TYPE;
D O I
10.1016/j.ceramint.2015.04.126
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
NaLi0.2Ni0.2Mn0.6O2 oxide with a layered P2-type structure is synthesized by the conventional solid-state reaction method and it is used as the cathode for sodium-ion batteries. In order to enhance the cycling ability of P-2-structured NaxMnO2 compounds, we partially substituted manganese by lithium and nickel. The shape of the NaLi0.2Ni0.2Mn0.6O2 particles is rectangular prismatic. The capacity of the NaLi0.2Ni0.2Mn0.6O2 cathode is 117 mA h g(-1) and 83 mA h g(-1) at 0.1 C and 1 C, respectively. The NaLi0.2Ni0.2Mn0.6O2 cathode exhibits excellent cycling ability with 88% capacity retention over 70 cycles. It is suggested that NaLi0.2Ni0.2Mn0.6O2 oxide is a promising cathode material for sodium-ion batteries. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:10199 / 10207
页数:9
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