TiO2@Sn core-shell nanotubes for fast and high density Li-ion storage material

被引:51
作者
Kim, Hyesun [2 ]
Kim, Min Gyu [1 ]
Shin, Tae Joo [1 ]
Shin, Hyun-Jun [1 ]
Cho, Jaephil [2 ]
机构
[1] Pohang Accelerator Lab, Beamline Res Div, Pohang 790784, South Korea
[2] Hanyang Univ, Dept Appl Chem, Ansan 426791, South Korea
关键词
TiO2@Sn core-shell; Nanotube; Li-ion cell; High density; Anode; Rate capability;
D O I
10.1016/j.elecom.2008.08.035
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
TiO2@Sn core-shell nanotube material prepared by thermal decomposition of SnCl4 on TiO2 nanotubes at 300 degrees C has been demonstrated superior Li-ion storage capability of 176 mA h/g even at high current rate of 4000 mA/g (charge and discharge of all TiO2 within 5 min) in spite of using low carbon content (5 wt%). This value corresponds to volumetric energy densities of 317 mA h/cm(3), and its value was 3.5-fold larger than that of the bare TiO2 nanotubes. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1669 / 1672
页数:4
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