A novel second-order non-linear optical coordination polymer with three-fold interpenetrated CdSO4-type network constructed by carboxylate-sulfonate ligands and strontium ions

被引：11

作者：

Guan, Lei ^{[1
]}

Wang, Ying ^{[2
]}

机构：

[1] Liaoning Univ Petr & Chem Engn, Sch Chem & Mat Sci, Fushun 113001, Peoples R China

[2] Liaoning Univ Petr & Chem Engn, Ctr Expt, Coll Chem Chem Engn & Environm Engn, Fushun 113001, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2015年 / 230卷

关键词：

Hydrothermal synthesis; Strontium; Property; Coordination polymer; METAL-ORGANIC FRAMEWORKS; COPPER(II) COMPLEXES; PHYSICAL-PROPERTIES; 1D CHAIN; CLUSTER;

D O I：

10.1016/j.jssc.2015.07.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel strontium carboxylate-sulfonate coordination polymer, [Sr(HSIP)(H2O)(3)](n)center dot nH(2)O (1) (NaH2SIP = 5-sulfoisophthalic monosodium salt) has been synthesized by hydrothermal reaction. It was characterized by X-ray single crystal diffraction, infrared spectroscopy, elemental and thermogravimetric analysis. Each strontium atom is eight-coordinate with a distorted bicapped trigonal prismatic arrangement. The whole HSIP2- ligand acts as a eta(5)mu(4) bridge to generate three-fold interpenetrated CdSO4-type network structure, which is constructed from the left- and right-handed helixes paralleled to each other bridged by the HSIP2- ligands. The luminescence spectrum indicates an emission maximum at 459 nm. Compound 1 shows a second harmonic generation (SHG) response that is 4 times that of KH2PO4. (C) 2015 Elsevier Inc. All rights reserved.

引用

页码：243 / 248

页数：6

共 48 条

[1] Pillar-layered Zn-triazolate-carboxylate frameworks tuned by the bend angles of ditopic ligands
Bai, Ni
Li, Shu'ni
Jiang, Yucheng
Hu, Mancheng
Zhai, Quanguo
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 53 : 84 - 87
[2] 1:2 and 1:1 Ag(I)-isonicotinamide coordination compounds:: Five-fold interpenetrated CdSO4 network and the first example of (pyridine)N-Ag-O(amide) bonds
Bhogala, BR
Thallapally, PK
Nangia, A
[J]. CRYSTAL GROWTH & DESIGN, 2004, 4 (02) : 215 - 218
[3] Synthesis, structure and magnetic properties of a pair of copper dicarboxylate/dipyridylamine coordination polymers with a non-interpenetrated CdSO4 topology
Braverman, Maxwell A.
Szymanski, Paul J.
Supkowski, Ronald M.
LaDuca, Robert L.
[J]. INORGANICA CHIMICA ACTA, 2009, 362 (10) : 3684 - 3690
[4] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores
Chen, BL
Eddaoudi, M
Hyde, ST
O'Keeffe, M
Yaghi, OM
[J]. SCIENCE, 2001, 291 (5506) : 1021 - 1023
[5] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n
Chui, SSY
Lo, SMF
Charmant, JPH
Orpen, AG
Williams, ID
[J]. SCIENCE, 1999, 283 (5405) : 1148 - 1150
[6] Coordination solids via assembly of adaptable components:: Systematic structural variation in alkaline earth organosulfonate networks
Côté, AP
Shimizu, GKH
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (21) : 5361 - 5370
[7] Dalrymple SA, 2002, CHEM-EUR J, V8, P3010, DOI 10.1002/1521-3765(20020703)8:13<3010::AID-CHEM3010>3.0.CO
[8] 2-5
[9] Three novel zinc(II) sulfonate-phosphonates with tetranuclear or hexanuclear cluster units
Du, Zi-Yi
Xu, Hai-Bing
Mao, Jiang-Gao
[J]. INORGANIC CHEMISTRY, 2006, 45 (16) : 6424 - 6430
[10] A new approach to novel cluster compounds of lead(II) phosphonates
Du, Zi-Yi
Xu, Hai-Bing
Li, Xiu-Ling
Mao, Jiang-Gao
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 28 (28) : 4520 - 4529

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