2-Aminopyridinium bis(pyridine-2,6-dicarboxylato)ferrate(III)

被引：4

作者：

Mirzaei, Masoud ^{[1
]}

Eshtiagh-Hosseini, Hossein ^{[1
]}

Mague, Joel T. ^{[2
]}

机构：

[1] Ferdowsi Univ Mashhad, Dept Chem, Mashhad 917791436, Iran

[2] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

关键词：

CRYSTAL-STRUCTURE; PROTON-TRANSFER; DIHYDRATE;

D O I：

10.1107/S1600536812001493

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, (C5H7N2)[Fe(C7H3NO4)(2)] or [2-apyH][Fe(pydc)(2)], the asymmetric unit contains an [Fe(pydc)(2)](-) (pydc is pyridine-2,6-dicarboxylate) anion and a protonated 2-aminopyridine cation ([2-apyH](+)). The complex anion contains an Fe-III atom within a distorted octahedral FeN2O4 coordination geometry. N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonding, offset pi-pi stacking [centroid-centroid distance = 3.805 (13) angstrom] and C-O center dot center dot center dot pi interactions [3.494 (14) angstrom] generate a three-dimensional network structure.

引用

页码：M174 / U872

页数：11

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