An Efficient and Facile Access to Substituted 1E,3E-Dienylphosphonates via Horner-Wadsworth-Emmons Olefination of α,β-Unsaturated Aldehydes with Tetraethyl Methylenebisphosphonate

被引：3

作者：

Yahyaoui, Marwa ^{[1
]}

Touil, Soufiane ^{[1
]}

Samarat, Ali ^{[1
]}

机构：

[1] Univ Carthage, Fac Sci Bizerte, Lab Heteroatom Organ Chem, Zarzouna 7021, Tunisia

来源：

CHEMISTRY LETTERS | 2018年 / 47卷 / 06期

关键词：

Dienylphosphonates; Horner-Wadsworth-Emmons; alpha; beta-Unsaturated aldehydes; CONVENIENT STEREOSELECTIVE-SYNTHESIS; CROSS-METATHESIS; PHOSPHINE OXIDE; ACID-DERIVATIVES; ALDER REACTION; RAW-MATERIALS; ETHYL-ESTER; 1,3-DIENES; 1,3-DIENYLPHOSPHONATES; PHOSPHONATES;

D O I：

10.1246/cl.180149

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An operationally simple and high-yielding synthetic method for 1E,3E-dienylphosphonates has been developed through the Horner-Wadsworth-Emmons olefination of alpha,beta-unsaturated aldehydes with tetraethyl methylenebisphosphonate, in heterogeneous medium, in the presence of solid potassium carbonate, in refluxing DMF.

引用

页码：729 / 731

页数：3

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