Metal complexes of polymeric tetrapyrazinoporphyrazine of the network structure: III. Catalytic properties

The catalytic properties of complexes of network polytetrapyrazinoporphyrazine with Cu2+, Co2+ and Fe2+ in the decomposition of hydrogen peroxide under heterogeneous conditions were studied. These compounds exhibit catalytic activity which depends on the nature of a metal ion. A comparison of the catalytic properties of the monomeric and polymeric isometallic complexes of tetrapyrazinoporphyrazine reveals an activating effect of the giant conjugated system of the polymeric macroligand.