Synthesis, Characterization and Investigation of Electrochemical and Spectroelectrochemical Properties of Peripherally Tetra Diethoxypropan Substituted Phthalocyanines

被引:2
作者
Akyuz, Duygu [1 ]
Akcay, Hakki Turker [2 ]
Bayrak, Riza [3 ]
机构
[1] Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey
[2] Recep Tayyip Erdogan Univ, Fac Arts & Sci, Dept Chem, Rize, Turkey
[3] Sinop Univ, Vocat Sch Hlth Serv, Dept Med Lab Tech, Sinop, Turkey
关键词
phthalocyanine; 1; 3-diethoxy-2-propanol; electrochemistry; spectroelectrochemistry; electrocolorimetry; METAL-FREE; ABSORPTION; ZINC(II); COPPER(II); COBALT;
D O I
10.1002/elan.202060250
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this study novel peripherally tetra 1,3-diethoxy-2-propanol substituted Co(II), Cu(II), Mg(II), Ni(II) Zn(II) phthalocyanine derivatives were prepared. The characterization of the novel compounds was made by FT-IR,H-1-NMR, UV-vis and MALDI-TOF mass. Electrochemical,in-situspectroelectrochemical and electrocolorimetric measurements have been carried out with the aim to determine the redox properties, to illuminate reaction mechanism and the effect of substituent and metal center. Moreover, the color properties and aggregation tendency of compounds were also investigated.
引用
收藏
页码:146 / 151
页数:6
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