Green Synthesis of Noble Nanometals (Au, Pt, Pd) Using Glycerol under Microwave Irradiation Conditions

被引:61
作者
Kou, Jiahui [1 ]
Bennett-Stamper, Christina [2 ]
Varma, Rajender S. [1 ]
机构
[1] US EPA, Sustainable Technol Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA
[2] US EPA, Water Supply Water Resources Div, Natl Risk Management Res Lab, Cincinnati, OH 45268 USA
关键词
Glycerol; Green synthesis; Noble metal; Microwave; Polyol processes; POLYOL SYNTHESIS; ASSISTED SYNTHESIS; SILVER NANOWIRES; NANOPARTICLES; GROWTH;
D O I
10.1021/sc400007p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A newer application of glycerol in the field of nanomaterials synthesis has been developed from both the economic and environmental points of view. Glycerol can act as a reducing agent for the fabrication of noble nanometals, such as Au, Pt, and Pd, under microwave irradiation. Their shapes can be changed by adding different surfactants. In the presence of CTAB, Au nanosheets were formed within 2 min where the size of Au nanosheets can be controlled by the microwave irradiation time and glycerol content.
引用
收藏
页码:810 / 816
页数:7
相关论文
共 33 条
[1]   Valorization of biodiesel derived glycerol as a carbon source to obtain added-value metabolites: Focus on polyunsaturated fatty acids [J].
Abad, Sergi ;
Turon, Xavier .
BIOTECHNOLOGY ADVANCES, 2012, 30 (03) :733-741
[2]   Microwave-Assisted Synthesis of Colloidal Inorganic Nanocrystals [J].
Baghbanzadeh, Mostafa ;
Carbone, Luigi ;
Cozzoli, P. Davide ;
Kappe, C. Oliver .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (48) :11312-11359
[3]   Chemical Kinetics of Gold Nanorod Growth in Aqueous CTAB Solutions [J].
Bullen, Craig ;
Zijlstra, Peter ;
Bakker, Eric ;
Gu, Min ;
Raston, Colin .
CRYSTAL GROWTH & DESIGN, 2011, 11 (08) :3375-3380
[4]   Low-temperature solution synthesis of nanocrystalline binary intermetallic compounds using the polyol process [J].
Cable, RE ;
Schaak, RE .
CHEMISTRY OF MATERIALS, 2005, 17 (26) :6835-6841
[5]   Sustainable Preparation of Supported Metal Nanoparticles and Their Applications in Catalysis [J].
Campelo, Juan M. ;
Luna, Diego ;
Luque, Rafael ;
Marinas, Jose M. ;
Romero, Antonio A. .
CHEMSUSCHEM, 2009, 2 (01) :18-45
[6]   Effect of impurities in biodiesel-derived waste glycerol on the performance and feasibility of biotechnological processes [J].
Chatzifragkou, Afroditi ;
Papanikolaou, Seraphim .
APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2012, 95 (01) :13-27
[7]  
Chiu CY, 2011, NAT CHEM, V3, P393, DOI [10.1038/nchem.1025, 10.1038/NCHEM.1025]
[8]   Polyol Synthesis of Silver Nanowires: An Extensive Parametric Study [J].
Coskun, Sahin ;
Aksoy, Burcu ;
Unalan, Husnu Emrah .
CRYSTAL GROWTH & DESIGN, 2011, 11 (11) :4963-4969
[9]   The hydrothermal synthesis of zeolites: History and development from the earliest days to the present time [J].
Cundy, CS ;
Cox, PA .
CHEMICAL REVIEWS, 2003, 103 (03) :663-701
[10]   Toward greener nanosynthesis [J].
Dahl, Jennifer A. ;
Maddux, Bettye L. S. ;
Hutchison, James E. .
CHEMICAL REVIEWS, 2007, 107 (06) :2228-2269