Construction of highly efficient non-enzymatic glucose sensors based on micro-spherical Ni-metal-organic frameworks

被引:8
作者
Chen, Junli [1 ]
Yin, Haoyong [1 ]
Zhao, Shumin [1 ]
Gong, Jianying [1 ]
Ji, Zhenguo [1 ]
Nie, Qiulin [1 ]
Wang, Ling [2 ]
机构
[1] Hangzhou Dianzi Univ, Coll Mat & Environm Engn, Hangzhou 310018, Peoples R China
[2] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Peoples R China
关键词
Non-enzymatic; glucose sensor; MOF; microspheres; CARBON; NANOPARTICLES; PERFORMANCE;
D O I
10.1142/S1793604720500228
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The Ni-metal-organic frameworks microspheres (Ni-BTC) were prepared and used directly to construct non-enzymatic glucose sensors. The Ni-BTC sensors displayed much higher glucose sensing performance than that of Ni-MOFs derived NiO, which showed wide detection regions of 5-3000 mu M and 3500-6000 mu M with the sensitivity of 932.68 mu A.mM(-1).cm(-2) and 273.04 mu A.mM(-1).cm(-2), respectively. Moreover, it also displayed good selectivity and favorable sensing feasibility for serum analysis. The high performance of the non-enzymatic glucose detection on Ni-BTC may be due to the highly efficient charge transfers during the electrocatalytic glucose oxidation process.
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页数:4
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