Thermal, mechanical, and optical studies of NaBr-added l-alanine crystal

被引:2
作者
Jayanalina, T. [1 ]
Rajarajan, G. [2 ]
Parthiban, S. [3 ]
Mojumdar, S. C. [4 ,5 ]
机构
[1] KSR Coll Engn, Dept Phys, Tiruchengode 637215, Tamil Nadu, India
[2] Mahendra Engn Coll, Dept Phys, Namakkal, Tamil Nadu, India
[3] Annamalai Univ, Dept Chem, Fac Engn & Technol, Annamalainagar 608002, Chidambaram, India
[4] Univ Guelph, Guelph, ON N1G 2W1, Canada
[5] Trencin Univ A Dubcek, Puchov, Slovakia
关键词
Crystal growth; Amino acid crystals; Thermal studies; TG-DTA; FT-IR; XRD; GROWTH; COMPLEXES; CHLORIDE;
D O I
10.1007/s10973-013-3058-7
中图分类号
O414.1 [热力学];
学科分类号
摘要
The 1:1 adduct of l-Alanine and sodium bromide (l-ANaBr) crystal has been grown from aqueous solution by a slow evaporation technique. l-alanine and sodium bromide were used in the ratio 1:1 for synthesis. Characterizations were carried out to study the thermal, optical, and mechanical properties of the grown crystal. Single-crystal X- ray diffraction analysis shows that the grown crystal belongs to the monoclinic system. The crystalline nature and its various planes of reflections were observed by powder XRD analysis. Thermal studies reveal that the crystal is stable up to 113.37 A degrees C. The chemical compositions of the grown crystal were determined by FT-IR spectral analysis. The transmittance, absorption, and reflection spectrum of l-ANaBr crystal studied using a UV-Vis spectrometer indicates that the crystal has good optical transparency. The mechanical property of the grown crystal studied using Vickers microhardness measurement reveals that the crystal is a soft material.
引用
收藏
页码:1025 / 1030
页数:6
相关论文
共 24 条
  • [1] BETAINE COMPOUNDS - A NEW FAMILY WITH FERROELECTRIC AND INCOMMENSURATE PHASES
    ALBERS, J
    [J]. FERROELECTRICS, 1988, 78 : 3 - 10
  • [2] p-N,N-dimethylaminobenzaldehyde (DAB) grown by solution technique using CCl4 as growth medium
    Anbusrinivasan, P.
    Madhurambal, G.
    Mojumdar, S. C.
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 96 (01) : 111 - 115
  • [3] Growth and characterization of organometallic L-alanine cadmium chloride single crystal by slow evaporation technique
    Bright, K. C.
    Freeda, T. H.
    [J]. PHYSICA B-CONDENSED MATTER, 2010, 405 (18) : 3857 - 3861
  • [4] Thermochemical study of sorption of pyridine derivates by copper forms of synthetic and natural zeolites
    Fortunova, L'.
    Rehakova, M.
    Nagyova, S.
    Dolinska, S.
    Mojumdar, S. C.
    Jona, E.
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2011, 104 (03) : 955 - 962
  • [5] Structure and vibrational spectra of L-alanine L-alaninium picrate monohydrate
    Ghazaryan, V. V.
    Fleck, M.
    Petrosyan, A. M.
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2012, 1015 : 51 - 55
  • [6] β-alanine-oxalic acid (1:1) hemihydrate crystal:: structure, 13C NMR and vibrational properties, protonation character
    Godzisz, D
    Ilczyszyn, M
    Ilczyszyn, MM
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (04) : 681 - 693
  • [7] Growth, spectroscopic, dielectric and nonlinear optical studies of semi organic nonlinear optical crystal - L-Alanine lithium chloride
    Hanumantharao, Redrothu
    Kalainathan, S.
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 86 : 80 - 84
  • [8] CHARACTERIZATION AND THERMAL PROPERTIES OF Ni-EXCHANGED MONTMORILLONITE WITH BENZIMIDAZOLE
    Jona, E.
    Sapietova, M.
    Snircova, S.
    Pajtasova, M.
    Ondrusova, D.
    Pavlik, V.
    Lajdova, L'.
    Mojumdar, S. C.
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 94 (01) : 69 - 73
  • [9] The application of Aj, BAC, I6, HOMA indexes for quantitative determination of aromaticity of metal complexes with benzoic, salicylic, nicotinic acids and benzene derivatives
    Kalinowska, M
    Siemieniuk, E
    Kostro, A
    Lewandowski, W
    [J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2006, 761 (1-3): : 129 - 141
  • [10] Kanagasabapathy K, 2012, OPTOELECTRON ADV MAT, V6, P218