Novel Cobalt Catalysts Supported on Metal-Organic Frameworks MIL-53(Al) for the Fischer-Tropsch Synthesis

被引：17
作者：
Sun, Buli [1 ,2 ]
Tan, Haiyan [3 ]
Liu, Sixu [1 ,2 ]
Lyu, Shuai [1 ,2 ]
Zhang, Xin [1 ,2 ]
Zhang, Yuhua [1 ,2 ]
Li, Jinlin [1 ,2 ]
Wang, Li [1 ,2 ]
机构：
[1] South Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Hubei, Peoples R China
[2] South Cent Univ Nationalities, Minist Educ, Coll Chem & Mat Sci, Wuhan 430074, Hubei, Peoples R China
[3] Hubei Univ Nationalities, Key Lab Biol Resources Protect & Utilizat Hubei P, Sch Chem & Environm Engn, Enshi 445000, Peoples R China
来源：
ENERGY TECHNOLOGY | 2019年 / 7卷 / 04期
关键词：
cobalt catalysts; Fischer-Tropsch synthesis; metal-organic frameworks; MIL-53(Al); ADSORPTION; PERFORMANCE; GASOLINE; PHASE; MOF;
D O I：
10.1002/ente.201800802
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Metal-organic framework of MIL-53(Al) (Al(OH)-[O2C-C6H4-CO2]) with exceptional thermal stability (as high as approximate to 550 degrees C in dynamic conditions) are synthesized via a solvothermal method, which serve as a porous host matrix of Co-based catalysts for Fischer-Tropsch synthesis (FTS). MIL-53(Al) shows large micropores and lattice dynamic flexibility, which make this material a promising support for active cobalt species. The as-synthesized Co/MIL-53(Al) catalysts with different cobalt loadings are characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), X-ray photoelectron spectroscopy (XPS), thermogravimetry (TG), Fourier-transform infrared (FT-IR) spectroscopy, and temperature programmed reduction. The results show that the immobilization of Co nanoparticles on the MIL-53(Al) support could be beneficial to obtain novel effective catalysts for FTS. Moreover, compared with the Co/gamma-Al2O3 catalyst of the same cobalt loading, the catalytic performance of Co/MIL-53(Al) catalyst shows higher FTS activity. Interestingly, the gasoline selectivity over the Co/MIL-53(Al) catalyst is much higher than that of the Co/gamma-Al2O3 catalyst, close to the optimal value for maximum gasoline and diesel production.
引用
收藏
页数：7
相关论文
共 30 条
  • [1] The frontiers of energy
    Armstrong, Robert C.
    Wolfram, Catherine
    de Jong, Krijn P.
    Gross, Robert
    Lewis, Nathan S.
    Boardman, Brenda
    Ragauskas, Arthur J.
    Ehrhardt-Martinez, Karen
    Crabtree, George
    Ramana, M. V.
    [J]. NATURE ENERGY, 2016, 1
  • [2] Cobalt particle size effects in the Fischer-Tropsch reaction studied with carbon nanofiber supported catalysts
    Bezemer, GL
    Bitter, JH
    Kuipers, HPCE
    Oosterbeek, H
    Holewijn, JE
    Xu, XD
    Kapteijn, F
    van Dillen, AJ
    de Jong, KP
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (12) : 3956 - 3964
  • [3] SAPO-34 seeds and membranes prepared using multiple structure directing agents
    Carreon, Moises A.
    Li, Shiguang
    Falconer, John L.
    Noble, Richard D.
    [J]. ADVANCED MATERIALS, 2008, 20 (04) : 729 - +
  • [4] Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules
    Chen, Banglin
    Ma, Shengqian
    Zapata, Fatima
    Fronczek, Frank R.
    Lobkovsky, Emil B.
    Zhou, Hong-Cai
    [J]. INORGANIC CHEMISTRY, 2007, 46 (04) : 1233 - 1236
  • [5] Advances in Catalysis for Syngas Conversion to Hydrocarbons
    Cheng, Kang
    Kang, Jincan
    King, David L.
    Subramanian, Vijayanand
    Zhou, Cheng
    Zhang, Qinghong
    Wang, Ye
    [J]. ADVANCES IN CATALYSIS, VOL 60, 2017, 60 : 125 - 208
  • [6] Co catalysts supported on oxidized CNTs: Evolution of structure during preparation, reduction and catalytic test in Fischer-Tropsch synthesis
    Chernyak, S. A.
    Suslova, E. V.
    Ivanov, A. S.
    Egorov, A. V.
    Maslakov, K. I.
    Savilv, S. V.
    Lunin, V. V.
    [J]. APPLIED CATALYSIS A-GENERAL, 2016, 523 : 221 - 229
  • [7] Isotropic and Anisotropic Growth of Metal-Organic Framework (MOF) on MOF: Logical Inference on MOF Structure Based on Growth Behavior and Morphological Feature
    Choi, Sora
    Kim, Taeho
    Ji, Hoyeon
    Lee, Hee Jung
    Oh, Moonhyun
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (43) : 14434 - 14440
  • [8] On the Origin of the Cobalt Particle Size Effects in Fischer-Tropsch Catalysis
    den Breejen, J. P.
    Radstake, P. B.
    Bezemer, G. L.
    Bitter, J. H.
    Froseth, V.
    Holmen, A.
    de Jong, K. P.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (20) : 7197 - 7203
  • [9] MOF positioning technology and device fabrication
    Falcaro, Paolo
    Ricco, Raffaele
    Doherty, Cara M.
    Liang, Kang
    Hill, Anita J.
    Styles, Mark J.
    [J]. CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) : 5513 - 5560
  • [10] Photocatalytic Fischer-Tropsch Synthesis on Graphene-Supported Worm-Like Ruthenium Nanostructures
    Guo, Xiao-Ning
    Jiao, Zhi-Feng
    Jin, Guo-Qiang
    Guo, Xiang-Yun
    [J]. ACS CATALYSIS, 2015, 5 (06): : 3836 - 3840
123