A Double-Walled Bimetal-Organic Framework for Antibiotics Sensing and Size-Selective Catalysis

被引：56

作者：

He, Hongming ^{[1
]}

Xue, Ya-Qi ^{[1
]}

Wang, Shu-Qi ^{[1
]}

Zhu, Qian-Qian ^{[1
]}

Chen, Jing ^{[1
]}

Li, Cheng-Peng ^{[1
]}

Du, Miao ^{[1
]}

机构：

[1] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, MOE Key Lab Inorgan Organ Hybrid Funct Mat Chem, Tianjin 300387, Peoples R China

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 24期

基金：

中国国家自然科学基金;

关键词：

GAS-ADSORPTION; SINGLE-CRYSTAL; BUILDING UNITS; METAL; MOF; CLUSTER; VERSATILE; LIGAND; STRATEGY; CAPTURE;

D O I：

10.1021/acs.inorgchem.8b01898

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first double-walled bimetal-organic framework [Cd4K4(TADA)(4)(H2O)(12)]center dot 6DMF (1, TADA = 3,3'-((6-hydroxy-1,3,5-triazine-2,4-diyObis(azanediyl)) dibenzoate) has been successfully constructed. In virtue of its high porosity and abundant basic sites, MOF 1 can be served as a high-efficiently size-selective heterogeneous catalyst for Knovenagel condensation reaction. Remarkably, 1 also exhibits excellent luminescent detectability for metronidazole (MDZ) with the highest quenching constant (K-sv) of 1.16 X 10(5) M-1. The results demonstrate that 1 can be served as a unique bifunctional platform for antibiotics sensing and size-selective catalysis.

引用

页码：15062 / 15068

页数：7

共 64 条

[41] Single-crystal structure validation with the program PLATON [J].

Spek, AL .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :7-13

[42] The First Example of Hetero-Triple-Walled Metal-Organic Frameworks with High Chemical Stability Constructed via Flexible Integration of Mixed Molecular Building Blocks [J].

Tian, Dan ;

Xu, Jian ;

Xie, Zhao-Jun ;

Yao, Zhao-Quan ;

Fu, Deng-Lin ;

Zhou, Zhen ;

Bu, Xian-He .

ADVANCED SCIENCE, 2016, 3 (10)

[43] A Mixed Molecular Building Block Strategy for the Design of Nested Polyhedron Metal-Organic Frameworks [J].

Tian, Dan ;

Chen, Qiang ;

Li, Yue ;

Zhang, Ying-Hui ;

Chang, Ze ;

Bu, Xian-He .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (03) :837-841

[44] Expanding Applications of Metal-Organic Frameworks: Zeolite Imidazolate Framework ZIF-8 as an Efficient Heterogeneous Catalyst for the Knoevenagel Reaction [J].

Tran, Uyen P. N. ;

Le, Ky K. A. ;

Phan, Nam T. S. .

ACS CATALYSIS, 2011, 1 (02) :120-127

[45] Metal-organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units [J].

Vodak, DT ;

Braun, ME ;

Kim, J ;

Eddaoudi, M ;

Yaghi, OM .

CHEMICAL COMMUNICATIONS, 2001, (24) :2534-2535

[46] Highly Stable Zr(IV)-Based Metal-Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water [J].

Wang, Bin ;

Lv, Xiu-Liang ;

Feng, Dawei ;

Xie, Lin-Hua ;

Zhang, Jian ;

Li, Ming ;

Xie, Yabo ;

Li, Jian-Rong ;

Zhou, Hong-Cai .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (19) :6204-6216

[47] An Anion Metal-Organic Framework with Lewis Basic Sites-Rich toward Charge-Exclusive Cationic Dyes Separation and Size-Selective Catalytic Reaction [J].

Wang, Xu-Sheng ;

Liang, Jun ;

Li, Lan ;

Lin, Zu-Jin ;

Bag, Partha Pratim ;

Gao, Shui-Ying ;

Huang, Yuan-Biao ;

Cao, Rong .

INORGANIC CHEMISTRY, 2016, 55 (05) :2641-2649

[48] Pd(II)-NHDC-Functionalized UiO-67 Type MOF for Catalyzing Heck Cross-Coupling and Intermolecular Benzyne-Benzyne-Alkene Insertion Reactions [J].

Wei, Yong-Liang ;

Li, Yue ;

Chen, Yun-Qi ;

Dong, Ying ;

Yao, Jia-Jia ;

Han, Xin-Yue ;

Dong, Yu-Bin .

INORGANIC CHEMISTRY, 2018, 57 (08) :4379-4386

[49] A highly stable and white-light-emitting Eu(III) MOF [J].

Wei, Yongqin ;

Sa, Rongjian ;

Wu, Kechen .

DALTON TRANSACTIONS, 2016, 45 (46) :18661-18667

[50] A stable Alq3@MOF composite for white-light emission [J].

Xie, Wei ;

He, Wen-Wen ;

Du, Dong-Ying ;

Li, Shun-Li ;

Qin, Jun-Sheng ;

Su, Zhong-Min ;

Sun, Chun-Yi ;

Lan, Ya-Qian .

CHEMICAL COMMUNICATIONS, 2016, 52 (16) :3288-3291

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