Selective recognition of aromatic hydrocarbons by endo-functionalized molecular tubes via C/N-H ••• π interactions

被引：31
|
作者：
Huang, Guo-Bao [1 ,2 ,3 ]
Liu, Wei-Er [3 ]
Valkonen, Arto [4 ,5 ]
Yao, Huan [3 ]
Rissanen, Kari [4 ,5 ]
Jiang, Wei [3 ]
机构：
[1] Yulin Normal Univ, Coll Chem & Food Sci, Yulin 537000, Peoples R China
[2] Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518060, Peoples R China
[3] South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Peoples R China
[4] Univ Jyvaskyla, Dept Chem, POB 3540014, Jyvaskyla, Finland
[5] Univ Jyvaskyla, Nanosci Ctr, POB 3540014, Jyvaskyla, Finland
来源：
CHINESE CHEMICAL LETTERS | 2018年 / 29卷 / 01期
基金：
芬兰科学院; 中国国家自然科学基金;
关键词：
Macrocycles; Aromatic hydrocarbon; Molecular recognition; Host-guest chemistry; Hydrogen bond; BIS-NAPHTHALENE; COMPLEXATION; MACROCYCLES; ENCAPSULATION; ENERGETICS; CAVITY; RINGS; WATER;
D O I：
10.1016/j.cclet.2017.07.005
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Molecular recognition of aromatic hydrocarbons by four endo-functionalized molecular tubes has been studied by H-1 NMR spectroscopy, computational methods, and single crystal X-ray crystallography. The binding selectivity is rationalized by invoking shape complementarity and dipole alignment. The non covalent interactions are proved to predominantly be C/N-H center dot center dot center dot pi interactions. (C) 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：91 / 94
页数：4
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