A ruthenium carbonyl cluster containing a hydroquinone ligand: A layered structure with a polymetallic species. Structure and electrochemical characterization

被引：9

作者：

Benito Pelayo-Vazquez, J. ^{[1
]}

Gonzalez, Felipe J. ^{[1
]}

Leyva, Marco A. ^{[1
]}

Campos, Myriam ^{[1
]}

Alfonso Torres, Luis ^{[1
]}

Rosales-Hoz, Maria J. ^{[1
]}

机构：

[1] IPN, Dept Quim, Ctr Invest & Estudios Avanzados, Mexico City 07360, DF, Mexico

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2012年 / 716卷

关键词：

Ruthenium cluster; Hydroquinone; Intermolecular contacts; Electrochemical; Electrode inhibition; ORGANOMETALLIC CRYSTALS; ACIDS;

D O I：

10.1016/j.jorganchem.2012.06.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Ru-3(CO)(12)] with 1,4-benzoquinone, in a hydrogen atmosphere led to the formation of a product with the formula [(mu-H)Ru-3(CO)(10)(mu(2)-O-C6H4OH)] which crystallizes with two molecules of free hydroquinone in the asymmetric unit with which it forms an arrangement of hydrogen bridges leading to a layered structure of trinuclear metallic and hydroquinone fragments. Electrochemical studies showed that electrode inhibition is obtained by cycling of the oxidation process of this compound. (C) 2012 Elsevier B. V. All rights reserved.

引用

页码：289 / 293

页数：5

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