Intensely phosphorescent block copolymer micelles containing gold(I) complexes

被引：4

作者：

Guo, Pingxia ^{[1
,2
]}

He, Qun ^{[1
,2
]}

Wang, Chen ^{[1
,2
]}

Hou, Zaili ^{[1
,2
]}

Yu, Bingran ^{[3
]}

Bu, Weifeng ^{[1
,2
]}

机构：

[1] Lanzhou Univ, Key Lab Nonferrous Met Chem & Resources Utilizat, State Key Lab Appl Organ Chem, Lanzhou, Gansu, Peoples R China

[2] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou, Gansu, Peoples R China

[3] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China

来源：

SOFT MATTER | 2018年 / 14卷 / 18期

关键词：

OPENING METATHESIS POLYMERIZATION; PLATINUM(II) COMPLEXES; UNIMOLECULAR MICELLES; VARIABLE QUALITY; NANOPARTICLES; POLYMERS; SOLVENTS; IONOMERS; NANOSTRUCTURES; ENHANCEMENTS;

D O I：

10.1039/c8sm00314a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrostatic combination of anionic block copolymers with cationic gold(i) complexes leads to the formation of spherical micelles, where gold(i)-containing ionic cores were formed with anionic blocks and further stabilized by neutral blocks of polystyrene or poly(ethylene oxide). This self-assembled strategy induces remarkable phosphorescence enhancement of the gold(i) complexes in solution. The emissive intensity increases unexpectedly with increasing molecular weight of the anionic block that is not coordinated onto the gold(i) complexes. The intensely phosphorescent micelles formed in water can be utilized as a luminescence bioimaging probe in living cells.

引用

页码：3521 / 3527

页数：7

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