Kinetic regularities and reaction products of adenosine triphosphoric acid with the thiosulfate-nitrosyl iron complex

被引：3

作者：

Psikha, B. L. ^{[1
]}

Saratovskikh, E. A. ^{[1
]}

Sanina, N. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2012年 / 61卷 / 09期

关键词：

adenosine triphosphoric acid; thiosulfate-nitrosyl iron complex; kinetic model; reaction rate constants; iron(II) complexes; iron(III) complexes;

D O I：

10.1007/s11172-012-0249-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetic characteristics of the reaction of adenosine triphosphoric acid (ATP) with the thiosulfate-nitrosyl iron complex (TNCI, donor of nitrogen monoxide) were obtained by the spectrofluorimetric method. The shape of the kinetic curves indicate a complicated mechanism of interaction between ATP and TNCI. The kinetic model for this process was proposed that satisfactorily describes the experimental data. The compositions and structures of the reaction products were determined. Iron in the reaction products is presented by two forms: Fe-II and Fe-III. The structures for the [ATP-Fe2+S] and [ATP-Fe3+S] complexes were proposed.

引用

页码：1810 / 1815

页数：6

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