Cerium-permanganate conversion coatings for a Zn-Co alloy

被引:20
作者
Bikulcius, G. [1 ]
Rucinskiene, A. [1 ]
Sudavicius, A. [1 ]
Burokas, V. [1 ]
Griguceviciene, A. [1 ]
机构
[1] Inst Chem, Dept Mat & Corros Res, LT-01018 Vilnius, Lithuania
关键词
Conversion coatings; Cerium; Permanganate; Zinc alloy;
D O I
10.1016/j.surfcoat.2008.08.041
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The present work aims at investigation of the corrosion resistance of cerium-permanganate conversion coatings (CPCC) electrolessly deposited on a Zn-Co (0.6%) alloy. For comparison, Zn-Co (0.6%) alloy with a commercial chromate treatment was also examined. CPCCs on a Zn-Co (0.6%) alloy have been studied by potentiodynamic polarization and the immersion test. The experimental results of potentiodynamic polarization and the immersion test showed that the corrosion resistance of CPCC on a Zn-Co (0.6%) alloy is close to the corrosion resistance of chromate conversion coating on Zn-Co (0.6%). The microstructure of conversion coatings was analysed by scanning electron microscopy (SEM) and the composition of conversion coatings was analysed by X-ray photoelectron spectroscopy (XPS). It has been found that the cerium-permanganate conversion coating is homogeneous as compared with the chromate coating. XPS has determined that the CPCC contains the following compounds: CeO2 (IV), Ce2O3(III) and Mn oxides and hydroxides. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:115 / 120
页数:6
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