Study on paper-structured catalyst for direct internal reforming SOFC fueled by the mixture of CH4 and CO2

被引：42

作者：

Shiratori, Yusuke ^{[1
,2
,3
]}

Ogura, Teppei ^{[2
,3
,5
]}

Nakajima, Hironori ^{[1
,2
]}

Sakamoto, Mio ^{[1
]}

Takahashi, Yutaro ^{[1
]}

Wakita, Yuto ^{[1
]}

Kitaoka, Takuya ^{[4
]}

Sasaki, Kazunari ^{[1
,2
,3
,5
]}

机构：

[1] Kyushu Univ, Fac Engn, Nishi Ku, Fukuoka 8190395, Japan

[2] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI, Nishi Ku, Fukuoka 8190395, Japan

[3] Kyushu Univ, Next Generat Fuel Cell Res Ctr, Nishi Ku, Fukuoka 8190395, Japan

[4] Kyushu Univ, Fac Agr, Higashi Ku, Fukuoka 8128581, Japan

[5] Kyushu Univ, Int Res Ctr Hydrogen Energy, Nishi Ku, Fukuoka 8190395, Japan

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2013年 / 38卷 / 25期

关键词：

Dry reforming; Biogas; Paper-structured catalyst; Solid oxide fuel cell; Direct internal reforming; CARBON DEPOSITION; BIOGAS; CELL; ELECTROLYTES; BEHAVIOR; METHANE;

D O I：

10.1016/j.ijhydene.2013.06.046

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Inorganic fiber network including YSZ fiber which acts as catalyst support was created by the simple paper-making process, and novel Ni-loaded paper-structured catalysts (PSCs) with excellent catalytic activity for the dry reforming of methane were designed and developed. The PSCs exhibited high fuel conversion comparable to the conventional powdered catalysts with less than one-tenth catalyst weights. The significant advantages of the PSCs are their high mechanical flexibility and material workability. So far, a functionally-graded catalytic reaction field which leads to uniform temperature distribution during biogas reforming resulting in stable operation of planar SOFC was successfully developed by the PSC array based on the kinetic simulation model, built in this research. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：10542 / 10551

页数：10

共 25 条

[1] CO2 reforming of CH4 over ceria-supported metal catalysts [J].

Asami, K ;

Li, XH ;

Fujimoto, K ;

Koyama, Y ;

Sakurama, A ;

Kometani, N ;

Yonezawa, Y .

CATALYSIS TODAY, 2003, 84 (1-2) :27-31

[2] Mechanical behaviour of ceramic oxygen ion-conducting membranes [J].

Atkinson, A ;

Selçuk, A .

SOLID STATE IONICS, 2000, 134 (1-2) :59-66

[3] Computational Investigation of Thermochemistry and Kinetics of Steam Methane Reforming on Ni(111) under Realistic Conditions [J].

Blaylock, D. Wayne ;

Ogura, Teppei ;

Green, William H. ;

Beran, Gregory J. O. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (12) :4898-4908

[4]

FUBINI B, 1989, SOLID STATE IONICS, V32, P273

[5] Methanol steam reforming over paper-like composites of Cu/ZnO catalyst and ceramic fiber [J].

Fukahori, S ;

Kitaoka, T ;

Tomoda, A ;

Suzuki, R ;

Wariishi, H .

APPLIED CATALYSIS A-GENERAL, 2006, 300 (02) :155-161

[6] Capturing of bisphenol A photodecomposition intermediates by composite TiO2-zeolite sheets [J].

Fukahori, S ;

Ichiura, H ;

Kitaoka, T ;

Tanaka, H .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 46 (03) :453-462

[7] Steam reforming behavior of methanol using paper-structured catalysts: Experimental and computational fluid dynamic analysis [J].

Fukahori, Shuji ;

Koga, Hirotaka ;

Kitaoka, Takuya ;

Nakamura, Mitsuyoshi ;

Wariishi, Hiroyuki .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (06) :1661-1670

[8] Carbon deposition in CH4/CO2 operated SOFC: Simulation and experimentation studies [J].

Girona, K. ;

Laurencin, J. ;

Fouletier, J. ;

Lefebvre-Joud, F. .

JOURNAL OF POWER SOURCES, 2012, 210 :381-391

[9] Experimental investigation of direct internal reforming of biogas in solid oxide fuel cells [J].

Lanzini, Andrea ;

Leone, Pierluigi .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (06) :2463-2476

[10] Room and high temperature failure mechanisms in solid oxide fuel cell electrolytes [J].

Lowrie, FL ;

Rawlings, RD .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2000, 20 (06) :751-760

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