Selective aerobic oxidation of amines to imines by TiO2 photocatalysis in water

被引：100

作者：

Li, Ning ^{[1
]}

Lang, Xianjun ^{[1
]}

Ma, Wanhong ^{[1
]}

Ji, Hongwei ^{[1
]}

Chen, Chuncheng ^{[1
]}

Zhao, Jincai ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 44期

关键词：

ELECTRON-TRANSFER; ALCOHOLS; EFFICIENT; OXIDE; ALDEHYDES; SYSTEM; ROUTE;

D O I：

10.1039/c3cc41407h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective oxidation of benzylic amines to imines with atmospheric O-2 is achieved in water on TiO2 under UV irradiation. The afforded imine could be easily separated and TiO2 can be recycled by filtration. To scale up, gram-scale imine products can be obtained.

引用

页码：5034 / 5036

页数：3

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