Development and experimental verification of a mathematical model of lithium ion battery

被引:5
|
作者
Bograchev, D. A. [1 ]
Vol'fkovich, Yu. M. [1 ]
Dubasova, V. S. [2 ]
Nikolenko, A. F. [2 ]
Ponomareva, T. A. [2 ]
Sosenkin, V. E. [1 ]
机构
[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia
[2] Sci Res Inst Elect Carbon Prod, Elektrougli 142455, Moscow Oblast, Russia
关键词
lithium-ion batteries; intercalation; extraction; lithium-nickel-cobalt oxide; graphite; porosimetry; solid-state diffusion; mathematical simulations; electric double layer; NEGATIVE ELECTRODE OPERATION; STANDARD POROSIMETRY; COMPUTER-SIMULATION; THERMAL-ANALYSIS; INSERTION; INTERCALATION; DIFFUSION; DISCHARGE; BEHAVIOR; CHARGE;
D O I
10.1134/S1023193513020031
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A model of the lithium ion battery is developed which takes into account intercalation and extraction of lithium ions in the active mass of negative and positive electrodes, the dependences of equilibrium electrode potentials on the concentration of intercalated lithium, the ion transfer in pores of electrodes and the separator, the kinetics of electrode reactions, and the electric double layer charging. As the active material for the negative electrode, UAMS graphite material is used. Lithium-nickel-cobalt oxide serves as the positive electrode. The porous structure of electrodes is studied by the method of standard contact porosimetry. Sufficiently high porosity values found for both electrodes (50% for anode and 27% for cathode) made it possible to consider the interface as regards the internal pore surface found from porosimetry data rather than as regards their external surface as in the previous studies. A comparison of calculated and experimental discharge curves demonstrates their closeness, which points to the correctness of the model. By the fitting procedure, the coefficients of solid-state diffusion of lithium ions and the rate constants for reactions on both electrodes are found.
引用
收藏
页码:115 / 123
页数:9
相关论文
共 50 条
  • [1] Development and experimental verification of a mathematical model of lithium ion battery
    D. A. Bograchev
    Yu. M. Vol’fkovich
    V. S. Dubasova
    A. F. Nikolenko
    T. A. Ponomareva
    V. E. Sosenkin
    Russian Journal of Electrochemistry, 2013, 49 : 115 - 123
  • [2] Thermal Model and Experimental Verification of Lithium-Ion Battery Based on Heat Generation Rate
    Zhai, Jiawei
    Jia, Zhixue
    Lei, Zhiguo
    JOURNAL OF ENERGY ENGINEERING, 2023, 149 (01)
  • [3] Lithium-ion battery model and experimental validation
    Berrueta, Alberto
    Irigaray, Victor
    Sanchis, Pablo
    Ursua, Alfredo
    2015 17TH EUROPEAN CONFERENCE ON POWER ELECTRONICS AND APPLICATIONS (EPE'15 ECCE-EUROPE), 2015,
  • [4] Experimental verification of lithium-ion battery prognostics based on an interacting multiple model particle filter
    Wang, Shuai
    Han, Wei
    Chen, Lifei
    Zhang, Xiaochen
    Pecht, Michael
    TRANSACTIONS OF THE INSTITUTE OF MEASUREMENT AND CONTROL, 2020,
  • [5] Mathematical Model of Lithium-Ion Battery Cell and Battery (Lib) on its Basis
    Smagin, D. I.
    Trofimov, A. A.
    Napreenko, K. S.
    Neveshkina, A. R.
    2019 WORKSHOP ON MATERIALS AND ENGINEERING IN AERONAUTICS, 2020, 714
  • [6] The Mathematical Model of 18650 Lithium-ion Battery in Electric Vehicles
    Amiribavandpour, Parisa
    Shen, Weixiang
    Kapoor, Ajay
    Shearer, Janine
    PROCEEDINGS OF THE 2013 IEEE 8TH CONFERENCE ON INDUSTRIAL ELECTRONICS AND APPLICATIONS (ICIEA), 2013, : 1264 - 1269
  • [7] Experimental assessment of the lumped lithium-ion battery model
    Ozdemir, Tanilay
    Amini, Ali
    Ekici, Ozgur
    Koksal, Murat
    XII INTERNATIONAL CONFERENCE ON COMPUTATIONAL HEAT, MASS AND MOMENTUM TRANSFER (ICCHMT 2019), 2019, 128
  • [8] Development of lithium ion battery
    Yoshino, A
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2000, 340 : 425 - 429
  • [9] Optimization of electrode loading amount in lithium ion battery by theoretical prediction and experimental verification
    Li, Xiang
    Tian, Shuo
    Liu, Zhifeng
    Xu, Na
    Liu, Runru
    Wang, Dejun
    Lu, Wei
    AIP ADVANCES, 2022, 12 (11)
  • [10] Mathematical model for thermal behavior of lithium ion battery pack under overcharge
    Qi, Chuang
    Zhu, Yanli
    Gao, Fei
    Yang, Kai
    Jiao, Qingjie
    INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2018, 124 : 552 - 563