One-pot, three-component synthesis of open-chain, polyfunctional sulfones

被引：0
|
作者：
Bouchez, L [1 ]
Vogel, P [1 ]
机构：
[1] Ecole Polytech Fed Lausanne, Inst Chim Mol & Biol, Lausanne, Switzerland
来源：
SYNTHESIS-STUTTGART | 2002年 / 02期
关键词：
ene-reaction; enoxysilanes; sulfinates; sulfones;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Silyl enol ethers of esters, ketones, as well as allylstannane and allylsilanes react with sulfur dioxide activated with t-BuMe2SiOSO2CF3 to give silyl sulfinates that can be reacted in the same pot with a variety of electrophiles generating the corresponding polyfunctional sulfones. The silyl sulfinate intermediates are formed via ene-reactions following probably concerted mechanisms.
引用
收藏
页码：225 / 231
页数：7
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