Oxidation using activated carbon and molecular oxygen system

被引:54
作者
hayashi, Masahiko [1 ]
机构
[1] Kobe Univ, Grad Sch Sci, Dept Chem, Kobe, Hyogo 6578501, Japan
关键词
oxidation; activated carbon; oxidative aromatization; heterocyclic compound;
D O I
10.1002/tcr.20152
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper describes the utility of an activated carbon-molecular oxygen system, not only in the oxidation of benzylic and allylic alcohols, but alos in teh direct carbonylation at the benzylic position. The preparation of a variety of heteroaromatic and aromatic compounds, including substituted pyridines, pyrazoles, benzoxazoles, benzimidazoles, benzothiazoles, 2-substituted imidazoles, indoles, pyrimidin-1(1H)-ones, and anthracenes, by oxidative aromatization using the activated carbon-molecular oxygen system is also discussed. (C) 2008 The Japan Chemical Journal Forum and Wiley Periodical, Inc.
引用
收藏
页码:252 / 267
页数:16
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