A nanocomposite of graphene/MnO2 nanoplatelets for high-capacity lithium storage

被引:40
作者
Li, Xinlu [1 ]
Song, Hongfang [1 ]
Wang, Hao [1 ]
Zhang, Yonglai [1 ]
Du, Kun [1 ]
Li, Hongyi [1 ]
Huang, Jiamu [1 ]
机构
[1] Chongqing Univ, Sch Mat Sci & Engn, Chongqing 400045, Peoples R China
基金
中国国家自然科学基金;
关键词
MnO2; Graphene nanosheets; Lithium ion batteries; ELECTROCHEMICAL PERFORMANCE; FACILE SYNTHESIS; ANODE MATERIAL; LI-STORAGE; NANOTUBE; ELECTRODES; BATTERIES; HYBRID;
D O I
10.1007/s10800-012-0488-z
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A nanocomposite of graphene/MnO2 nanoplatelets was prepared by one-step chemistry route at room temperature. The microstructure was characterized by X-ray diffraction, N-2 absorption, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Both TEM and SEM images show that MnO2 nanoplatelets are homogeneously distributed on the graphene nanosheets. The electrochemical properties were tested by cyclic voltammetry, galvanostatic charge-discharge experiments. The nanocomposite exhibited high lithium capacity (905 mAh g(-1) at 100 mA g(-1)). The superior lithium storage capability can be attributed to the "open" structure: the large effective surface area and short diffusion paths.
引用
收藏
页码:1065 / 1070
页数:6
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