Amphiphilic N-methylimidazole-functionalized diblock copolythiophenes

被引：21

作者：

Ghoos, Toon ^{[1
]}

Van den Brande, Niko ^{[2
]}

Defour, Maxime ^{[2
]}

Brassinne, Jeremy ^{[3
]}

Fustin, Charles-Andre ^{[3
]}

Gohy, Jean-Francois ^{[3
]}

Hoeppener, Stephanie ^{[4
]}

Schubert, Ulrich S. ^{[4
]}

Vanormelingen, Wouter ^{[1
,5
]}

Lutsen, Laurence ^{[1
,5
]}

Vanderzande, Dirk J. ^{[1
,5
]}

Van Mele, Bruno ^{[2
]}

Maes, Wouter ^{[1
,5
]}

机构：

[1] Hasselt Univ, Inst Mat Res IMO IMOMEC, B-3590 Diepenbeek, Belgium

[2] Vrije Univ Brussel, Phys Chem & Polymer Sci FYSC, B-1050 Brussels, Belgium

[3] Inst Condensed Matter & Nanosci IMCN, Bio & Soft Matter Div BSMA, B-1348 Louvain, Belgium

[4] Univ Jena, Lab Organ & Macromol Chem, D-07743 Jena, Germany

[5] IMEC, IMOMEC Assoc Lab, B-3590 Diepenbeek, Belgium

来源：

EUROPEAN POLYMER JOURNAL | 2014年 / 53卷

关键词：

Diblock copolymers; Ionic polythiophenes; Solution properties; Dynamic light scattering; Thermal properties; Organic photovoltaics; HETEROJUNCTION SOLAR-CELLS; CHAIN-GROWTH POLYMERIZATION; MOLECULAR-WEIGHT; POLYTHIOPHENE; POLYELECTROLYTE; COPOLYMERS; POLY(3-HEXYLTHIOPHENE); PERFORMANCE; MORPHOLOGY; METATHESIS;

D O I：

10.1016/j.eurpolymj.2014.01.028

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Amphiphilic diblock copolythiophenes are synthesized by an efficient two-step synthetic strategy. The block architecture is created via the quasi-living Grignard metathesis reaction, after which ionic imidazolium moieties are introduced by substitution on the bromohexyl side chains of one of the monomer constituents. The compositional influence on the solution behavior and thermal properties of both the precursor and ionic block copolythiophenes is investigated. The novel materials are of particular appeal for integration in organic solar cell stacks, either as active layer or interlayer materials. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：206 / 214

页数：9

共 61 条

[41] Safe and convenient procedure for solvent purification [J].

Pangborn, AB ;

Giardello, MA ;

Grubbs, RH ;

Rosen, RK ;

Timmers, FJ .

ORGANOMETALLICS, 1996, 15 (05) :1518-1520

[42] Hybrid Semiconductor Nanoparticles: π-Conjugated Ligands and Nanostructured Films [J].

Park, Yushin ;

Advincula, Rigoberto C. .

CHEMISTRY OF MATERIALS, 2011, 23 (19) :4273-4294

[43] Enhanced Performance of Bulk Heterojunction Solar Cells Using Block Copoly(3-alkylthiophene)s [J].

Ren, Guoqiang ;

Wu, Pei-Tzu ;

Jenekhe, Samson A. .

CHEMISTRY OF MATERIALS, 2010, 22 (06) :2020-2026

[44] Water- and Ionic-Liquid-Soluble Branched Polythiophenes Bearing Anionic and Cationic Moieties [J].

Richter, Thomas V. ;

Bueher, Christian ;

Ludwigs, Sabine .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (01) :43-46

[45] Improved High-Efficiency Organic Solar Cells via Incorporation of a Conjugated Polyelectrolyte Interlayer [J].

Seo, Jung Hwa ;

Gutacker, Andrea ;

Sun, Yanming ;

Wu, Hongbin ;

Huang, Fei ;

Cao, Yong ;

Scherf, Ullrich ;

Heeger, Alan J. ;

Bazan, Guillermo C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (22) :8416-8419

[46] Chain growth mechanism for regioregular nickel-initiated cross-coupling polymerizations [J].

Sheina, EE ;

Liu, JS ;

Iovu, MC ;

Laird, DW ;

McCullough, RD .

MACROMOLECULES, 2004, 37 (10) :3526-3528

[47] End Group-Functionalization and Synthesis of Block-Copolythiophenes by Modified Nickel Initiators [J].

Smeets, Alfons ;

Willot, Pieter ;

De Winter, Julien ;

Gerbaux, Pascal ;

Verbiest, Thierry ;

Koeckelberghs, Guy .

MACROMOLECULES, 2011, 44 (15) :6017-6025

[48] Synthesis and Self-Assembly of Thiophene-Based All-Conjugated Amphiphilic Diblock Copolymers with a Narrow Molecular Weight Distribution [J].

Song, In Young ;

Kim, Jinseck ;

Im, Min Jeong ;

Moon, Byung Joon ;

Park, Taiho .

MACROMOLECULES, 2012, 45 (12) :5058-5068

[49] Amphiphilic conjugated block copolymers for efficient bulk heterojunction solar cells [J].

Suspene, C. ;

Miozzo, L. ;

Choi, J. ;

Gironda, R. ;

Geffroy, B. ;

Tondelier, D. ;

Bonnassieux, Y. ;

Horowitz, G. ;

Yassar, A. .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (10) :4511-4518

[50] AB Block Copoly(3-alkylthiophenes): Synthesis and Chiroptical Behavior [J].

Verswyvel, Michiel ;

Monnaie, Frederic ;

Koeckelberghs, Guy .

MACROMOLECULES, 2011, 44 (24) :9489-9498

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