Synthesis and crystal structure of Cu2[bbirnb]: A metal-organic framework with zeolite ABW topology

被引：12
作者：
Zhang, Lirong [1 ]
Qu, Xuejian [1 ]
Bi, Minghui [1 ]
Wang, Shuang [1 ]
Gong, Shuzhe [1 ]
Huo, Qisheng [1 ]
Liu, Yunling [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
MICROPOROUS AND MESOPOROUS MATERIALS | 2009年 / 119卷 / 1-3期
基金：
中国国家自然科学基金;
关键词：
Solvothermal synthesis; Crystal structure; Metal-organic framework; Imidazolate derivate; IMIDAZOLATE FRAMEWORKS; COORDINATION POLYMERS; CENTER-DOT; DESIGN; COMPLEXES; ZMOFS; CAGES;
D O I：
10.1016/j.micromeso.2008.10.037
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A new copper(I) imidazolate metal-organic framework, Cu-2[bbimb] (1), has been synthesized by solvo-thermal reaction of Cu(NO3)(2) center dot 3H(2)O and 1,3-bis(2-benzimidazol)benzene (H(2)bbimb) in an ammonium/methanol mixture. Single-crystal X-ray diffraction analysis reveals that the structure of compound I contains three crystallographically independent Cu(I) ions and one bbimb(2-) ligand. Each copper center in I is linearly coordinated by two nitrogen atoms from two different bbimb ligands and each bbimb coordinates four copper ions to form a neutral three-dimensional metal-organic framework with zeolite ABW topology. Crystal data for 1: Monoclinic, C2/c, a = 22.1660(9) angstrom, b = 14.9825(7) angstrom, c = 11.4773(4) angstrom, beta = 107.972(2)degrees, V = 3625.7(3) angstrom(3), Z = 8. (C) 2008 Elsevier Inc. All rights reserved.
引用
收藏
页码：344 / 348
页数：5
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