A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand

被引：0
作者：
Ma, Qing-Yu [1 ]
Guan, Rui-Fang [1 ]
Li, Guo-Zhong [1 ]
Wang, Deng-Xu [2 ]
机构：
[1] Univ Jinan, Sch Mat Sci & Engn, Jinan 250022, Peoples R China
[2] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
来源：
APPLIED MECHANICS AND MATERIALS I, PTS 1-3 | 2013年 / 275-277卷
关键词：
Metal-Organic Frameworks; Silicon-Cored; Tetrahedral Ligands; Imidazole; COORDINATION POLYMERS; COMPLEXES;
D O I：
10.4028/www.scientific.net/AMM.275-277.2367
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A novel metal-organic framework, MnCl2(BIPS)(2)center dot 2CH(3)OH center dot 2H(2)O (1), was synthesized from MnCl2 and a tetrahedral silicon-cored ligand, Me2Si(p-C6H4-imdazol-1-y1)(2) (BIPS) under the slow diffusion method. The structure was determined by single-crystal X-ray diffraction. Complex 1 is a 2D sheet structure constructed from 1D chains with 34-atom metallamacrocycles.
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页码：2367 / +
页数：2
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