An Efficient Method to Separate Sc3N@C80 Ih and D5h Isomers and Sc3N@C78 by Selective Oxidation with Acetylferrocenium [Fe(COCH3C5H4)Cp]+

被引：22

作者：

Ceron, Maira R. ^{[1
]}

Li, Fang-Fang ^{[1
]}

Echegoyen, Luis ^{[1
]}

机构：

[1] Univ Texas El Paso, Dept Chem, El Paso, TX 79968 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 23期

基金：

美国国家科学基金会;

关键词：

endohedral metallofullerenes; geometric isomers; oxidation; reduction; scandium; ENDOHEDRAL METALLOFULLERENES; HIGH-YIELD; D-5H; FULLERENES; PURIFICATION; CATION; STATE; CAGE;

D O I：

10.1002/chem.201204219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on the different oxidation potentials of endohedral fullerenes Sc3N@C80 Ih and D5h and Sc3N@C78, an efficient and useful method that avoids HPLC has been developed for their separation. Selective chemical oxidation of the Sc3N@D5h-C80 isomer and Sc3N@C78 by using an acetylferrocenium salt [Fe(COCH3C5H4)Cp]+ followed by column chromatographic separation and reduction with CH3SNa resulted in the isolation of pure Sc3N@Ih-C80, Sc3N@C78, and a mixture of Sc3N@D5h-C80 and Sc3N@C68.

引用

页码：7410 / 7415

页数：6

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